Epoxy Resin Composition with Active Ester and Cyanate Ester for Low Dielectric Loss

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Solution Overview

Problem

There is a demand for printed circuit boards with low dielectric loss to reduce signal transmission losses in high-frequency regions while maintaining reliability, which existing technologies have not adequately addressed.

Innovation Solution

A resin composition for printed circuit boards is developed, comprising an epoxy resin, an active ester hardening agent, and a cyanate ester hardening agent, which reacts to form a structure with low polarizability, reducing dielectric loss and improving peel strength and processability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional hardening agents are used with epoxy resin, then adhesion and processability are improved, but dielectric loss increases in high-frequency regions

Engineering Contradiction:
Improvedielectric lossVSAvoidadhesion and processability
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent uses a composite hardening system combining active ester hardening agent and cyanate ester hardening agent with epoxy resin. This composite material approach creates a multi-functional curing system where the active ester provides adhesion and processability while the cyanate ester contributes to low dielectric loss, achieving both requirements simultaneously through material composition rather than single-material optimization

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the molecular structure parameters of the hardening agents by selecting specific active ester compounds with particular functional groups and cyanate ester compounds with specific aromatic ring structures. By changing the chemical parameters (molecular weight, functional group types, aromatic content) of the hardening agents, the resin composition achieves reduced polarizability and lower dielectric loss while maintaining adequate adhesion and processability

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If resin composition is optimized for low dielectric loss, then signal transmission loss is reduced, but peel strength and processability may deteriorate

Engineering Contradiction:
Improvesignal transmission lossVSAvoidpeel strength
Core Design Contradiction:
Loss of energyVSStrength

Solution Approach 1:

The patent merges the functions of two different hardening agents into a single curing system. The active ester hardening agent provides the necessary adhesion and processability characteristics, while the cyanate ester hardening agent contributes to low dielectric loss. By combining these two agents in specific proportions, the resin composition achieves both low signal transmission loss and adequate peel strength that neither agent could achieve alone

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent applies different functional properties to different components of the hardening system. The active ester component is optimized for interfacial adhesion and processability, while the cyanate ester component is optimized for bulk dielectric properties. This local optimization of different regions of the chemical system allows the overall material to satisfy conflicting requirements for both strength and low energy loss

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resin composition effectively lowers dielectric loss, enhances peel strength, and improves adhesion and processability, making it suitable for use as an insulating material in printed circuit boards to reduce signal transmission losses.

Implementation Method 1

an active ester hardening agent configured to react with the epoxy resin

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

a cyanate ester hardening agent

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Data Source

PatentUS10626288B2Resin composition for printed circuit board, resin varnish using the same, adhesive film, prepreg and printed wiring board
Publication Date: 2020.04.21 SAMSUNG ELECTRO MECHANICS CO LTD
  • US10626288B2 patent drawing
  • US10626288B2 patent drawing
  • US10626288B2 patent drawing

AI summary

A resin composition for a printed circuit board includes an epoxy resin; an active ester hardening agent configured to react with the epoxy resin; and a cyanate ester hardening agent.