Ether-Based Resist Protection Film Composition

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Solution Overview

Problem

Conventional resist protection film compositions using alcohol as solvents often damage the resist film, leading to T-top shaped patterns and surface roughness, and are limited by the structure of the polymer used, making it difficult to form high-quality rectangular resist patterns.

Innovation Solution

A composition using an alkali-soluble polymer combined with an ether-based solvent is developed, allowing for the formation of a resist protection film that reduces film damage and enables the creation of good rectangular resist patterns, regardless of the polymer structure, through the use of ether-based solvents which have a smaller solubility parameter than alcohol-based solvents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If alcohol-based solvents are used in resist protection film composition, then the film can be formed, but the resist film is damaged and pattern quality deteriorates

Engineering Contradiction:
Improveresist protection film formationVSAvoidresist pattern shape and surface quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the solvent type from alcohol-based to ether-based, altering the chemical parameters of the composition. This parameter change resolves the contradiction by enabling film formation while eliminating damage to the resist film, producing high-quality rectangular patterns without T-top deformation or surface roughness.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If alcohol-based solvents are used, then the composition can be applied, but the applicability is limited by polymer structure

Engineering Contradiction:
Improvepolymer structure compatibilityVSAvoidresist pattern formation process
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The ether-based solvent provides universal compatibility with various polymer structures in resist compositions. Unlike alcohol-based solvents that are limited by polymer structure, the ether-based solvent can be used with different polymer types, making the composition universally applicable while maintaining ease of manufacture and high-pattern quality.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Device complexity

If conventional alcohol-based composition is used, then the process is simple, but the resist film suffers damage and swelling

Engineering Contradiction:
Improvecomposition simplicityVSAvoidresist film damage and swelling
Core Design Contradiction:
Device complexityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the solvent parameter from alcohol to ether, which fundamentally alters the interaction with the resist film. This parameter change eliminates harmful effects such as film damage and swelling while maintaining the simplicity of the composition and application process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ether-based solvent composition minimizes resist film damage and allows for the formation of high-quality rectangular resist patterns, improving the resist pattern formation process and enhancing production efficiency.

Implementation Method 1

a composition for forming a resist protection film on a resist film and contains (a) an alkali-soluble polymer and (b) an ether-based solvent

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentUS8409781B2Composition for formation of resist protection film, and method for formation of resist pattern using the same
Publication Date: 2013.04.02 TOKYO OHKA KOGYO CO LTD
  • US8409781B2 patent drawing
  • US8409781B2 patent drawing
  • US8409781B2 patent drawing

AI summary

Disclosed are: a composition for forming a resist protection film, which shows less damage to a resist film, can form a good, rectangular resist pattern, and can be used regardless of the structure of a resin used in a resist composition; and a method for forming a resist pattern by using the composition. Specifically, disclosed are: a composition for forming a resist protection film, which comprises (a) an alkali-soluble polymer and (b) an ether-based solvent; and a method for forming a resist pattern by using the composition.