Ferroelectric Gate Stack Tunnel Dielectric Insert for NAND Memory

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Solution Overview

Problem

The existing 3D NAND flash technology faces challenges in achieving a large enough memory window (MW) to support multi-bit operation while maintaining the thickness constraints of the ferroelectric gate stack, which affects the scalability and efficiency of the technology.

Innovation Solution

Incorporating a tunnel dielectric layer (TDL) within the ferroelectric gate stack, which divides the ferroelectric layer into separate regions, effectively enhancing the memory window by leveraging trap dynamics and dipole engineering.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the thickness of the ferroelectric layer is increased to enhance memory window, then the memory window increases, but the thickness limit of 3D-NAND is exceeded and ferroelectricity is lost

Engineering Contradiction:
Improvememory windowVSAvoidthickness of ferroelectric layer
Core Design Contradiction:
ReliabilityVSLength of stationary object

Solution Approach 1:

The ferroelectric layer is divided into multiple thinner ferroelectric sub-layers separated by tunnel dielectric layers. This segmentation allows the total memory window to be accumulated across multiple interfaces while each individual ferroelectric sub-layer remains within the thickness limit to maintain ferroelectricity. The tunnel dielectric layers with trap states contribute additional memory window at each interface.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The gate stack employs a composite structure combining multiple ferroelectric materials and tunnel dielectric materials. The tunnel dielectric layers contain trap states that work synergistically with the ferroelectric layers to enhance the overall memory window. This composite approach allows achieving higher memory window without increasing the total thickness beyond 3D-NAND limits.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the thickness of the ferroelectric layer is increased to achieve theoretical maximum memory window, then memory window approaches 2Ec*tf, but practical MW is limited to ≤3 V due to charge injection and trapping effects

Engineering Contradiction:
Improvememory windowVSAvoidcharge injection and trapping effects
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

Tunnel dielectric layers are introduced as intermediary layers between the ferroelectric layers. These tunnel dielectric layers contain trap states that act as mediators to manage charge injection and trapping effects. The traps in the tunnel dielectric layers capture excess charges that would otherwise degrade the memory window, thereby protecting the ferroelectric layers and enabling practical MW to exceed the conventional 3V limit.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention converts the harmful charge trapping effects into a beneficial mechanism. By intentionally introducing trap states in the tunnel dielectric layers, these traps serve to stabilize the ferroelectric polarization states and enhance the memory window. The charge trapping that would normally be harmful is now utilized to create additional memory window through the trap-assisted tunneling and polarization control mechanisms.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Quantity of substance

If Z-pitch scaling is aggressive to enable massive bit cell density, then bit cell density increases, but gate control is reduced and write voltage increases

Engineering Contradiction:
Improvebit cell densityVSAvoidwrite voltage
Core Design Contradiction:
Quantity of substanceVSPower

Solution Approach 1:

The invention changes the electrical parameters of the gate stack by introducing tunnel dielectric layers with specific trap densities and energy levels. This parameter change enables achieving the same or higher memory window with lower write voltages. The trap states in the tunnel dielectric layers assist in polarization switching at lower voltages, thereby reducing the power requirement for write operations while maintaining high bit cell density achieved through Z-pitch scaling.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The insertion of the tunnel dielectric layer significantly increases the memory window, enabling multi-bit operation while maintaining the thickness limits of the NAND technology, thereby enhancing the scalability and efficiency of the ferroelectric gate stack.

Implementation Method 1

effectively enhancing the memory window by leveraging trap dynamics and dipole engineering

Methodology Applied
Scientific EffectTrap dynamics:

Implementation Method 2

effectively enhancing the memory window by leveraging trap dynamics and dipole engineering

Methodology Applied
Scientific EffectDipole engineering:

Implementation Method 3

the plurality of ferroelectric layers including a first ferroelectric layer and a second ferroelectric layer

Methodology Applied
Scientific EffectFerroelectricity:

Data Source

PatentUS20250194095A1Ferroelectric gate stack with tunnel dielectric insert for NAND applications
Publication Date: 2025.06.12 SAMSUNG ELECTRONICS CO LTD
  • US20250194095A1 patent drawing
  • US20250194095A1 patent drawing
  • US20250194095A1 patent drawing

AI summary

A ferroelectric gate stack may include a semiconductor layer, a conductor layer facing the semiconductor layer, a plurality of ferroelectric layers spaced apart from each other between the semiconductor layer and the conductor layer, a tunnel dielectric layer between a first ferroelectric layer and a second ferroelectric layer among the plurality of ferroelectric layers, and an interface layer between the semiconductor layer and the first ferroelectric layer.