Modified Flotation Test for In-Situ Reservoir Wettability

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Solution Overview

Problem

Current wettability testing methods for oil reservoirs fail to accurately measure and predict in-situ wettability due to the lack of control over pH conditions, which is crucial for understanding and modifying wettability to enhance oil recovery, as they do not replicate the in-situ pH of the reservoir.

Innovation Solution

A modified flotation test method that controls the experimental pH of the test vessel to match the in-situ pH of the oil reservoir by adjusting the gas/liquid phase chemistry, including the partial pressure of CO2, to accurately measure wettability and determine equilibrium constants for geochemical models, allowing for the design of injected water to optimize oil recovery.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional wettability testing methods are used without controlling pH conditions, then the testing procedure is simple and quick, but the measurement precision of in-situ wettability is poor

Engineering Contradiction:
Improvewettability measurement accuracyVSAvoidtesting procedure complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by controlling the pH of the aqueous phase in the flotation test to match the in-situ reservoir pH conditions. This involves adjusting chemical parameters (pH, ionic strength, gas composition) to replicate reservoir environment, thereby improving wettability measurement accuracy while maintaining a relatively simple flotation test framework

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If in-situ reservoir conditions are replicated in the flotation test, then the wettability measurement accuracy improves, but the device complexity and operational complexity increase

Engineering Contradiction:
Improvein-situ wettability measurement accuracyVSAvoidtesting operation simplicity
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The patent applies preliminary action by pre-calculating and preparing the aqueous phase composition to match in-situ reservoir conditions before conducting the flotation test. The pH and chemical composition are adjusted in advance based on known reservoir parameters, so that when the test is performed, the conditions are already optimized for accurate measurement without requiring complex real-time adjustments during operation

Inventive Principle:
Principle #10Preliminary action

3Reliability

If the aqueous phase chemistry is controlled to match in-situ conditions, then the reliability of wettability predictions improves, but the time required for test preparation and execution increases

Engineering Contradiction:
Improvewettability prediction reliabilityVSAvoidtest preparation and execution time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent applies preliminary action by pre-determining the aqueous phase composition based on reservoir data before the flotation test. The pH, ionic strength, and gas composition are calculated and prepared in advance, allowing the actual test to proceed quickly under pre-optimized conditions that ensure reliable wettability predictions

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach provides more accurate wettability measurements and predictions, enabling the modification of wettability for improved oil recovery by ensuring that the experimental conditions closely resemble the in-situ conditions of the oil reservoir, thereby optimizing the interaction between injected water and the reservoir rock and oil.

Implementation Method 1

controlling a chemistry of the gas/liquid phase sample to achieve an experimental pH value in the test vessel corresponding to conditions of the oil reservoir of interest

Methodology Applied
Scientific EffectCarbon dioxide dissolution and carbonic acid formation:

Implementation Method 2

Wettability describes the preference of a solid surface to be in contact with one fluid rather than another fluid. This preference is based on atomic-scale surface and interfacial forces

Methodology Applied
Scientific EffectWettability: Wetting

Data Source

PatentUS11420214B2Modified flotation test with in-situ reservoir conditions
Publication Date: 2022.08.23 ESAL TECHNOLOGIES LLC
  • US11420214B2 patent drawing
  • US11420214B2 patent drawing
  • US11420214B2 patent drawing

AI summary

Measurement of in-situ petroleum reservoir wettability at the current salinity and at different salinities and water compositions. That data may be used to derive the crude oil acid and base equilibrium constants for the oil-surface adhesion reaction that control wettability. These constants may be used in quantitative models of the reservoir wettability. This procedure produces an accurate description of reservoir wettability and identifies the specific water chemistry that will optimize in-situ wettability and, in turn, oil production.