Fluoropolymer SiOx Composition for Oxygen Adsorption and Heat Resistance

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Solution Overview

Problem

Existing compositions containing fluorine-containing polymers lack a specific silicon oxide that can effectively adsorb oxygen, which is crucial for reducing oxygen concentration in sealed spaces and enhancing heat resistance and plasma resistance.

Innovation Solution

A composition comprising a fluorine-containing polymer and 0.1-50 parts by mass of a silicon oxide of the formula SiOx, where 0 < x < 2, which adsorbs oxygen and improves the heat and plasma resistance of crosslinked products.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional fluorine-containing polymer compositions are used for sealing materials, then heat resistance and chemical resistance are achieved, but oxygen adsorption capability is insufficient

Engineering Contradiction:
Improveheat resistanceVSAvoidoxygen adsorption capability
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent combines fluorine-containing polymer with non-stoichiometric silicon oxide (SiOx where 0 < x < 2) to create a composite material that simultaneously achieves heat resistance from the polymer and oxygen adsorption capability from the silicon oxide, resolving the contradiction between thermal stability and oxygen uptake

Inventive Principle:
Principle #40Composite materials

2Temperature

If fluorine-containing polymer is used in high-temperature environments, then thermal stability is maintained, but plasma resistance deteriorates

Engineering Contradiction:
Improvethermal stabilityVSAvoidplasma resistance
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The composite structure combines the thermal stability of fluorine-containing polymer with the plasma resistance of non-stoichiometric silicon oxide, where the silicon oxide component provides protection against plasma damage while the polymer maintains thermal stability at high temperatures

Inventive Principle:
Principle #40Composite materials

3Stability of the object's composition

If stoichiometric silicon oxide is used, then chemical inertness is achieved, but oxygen adsorption is insufficient

Engineering Contradiction:
Improvechemical inertnessVSAvoidoxygen adsorption capacity
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The patent changes the compositional parameter of silicon oxide from stoichiometric (SiO2) to non-stoichiometric (SiOx where 0 < x < 2), creating deficiency sites that enable oxygen adsorption while maintaining chemical stability, thus resolving the contradiction between inertness and oxygen uptake capacity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively adsorbs oxygen, reducing its concentration in sealed spaces, and provides crosslinked products with enhanced heat resistance and plasma resistance.

Implementation Method 1

a non-stoichiometric silicon oxide (SiOx where 0 < x < 2) is used, with a specific silicon to oxygen atomic ratio and particle size, which adsorbs oxygen when heated

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP4043522B1Composition containing fluorine-containing polymer and crosslinked article
Publication Date: 2025.03.05 DAIKIN INDUSTRIES LTD
  • EP4043522B1 patent drawing
  • EP4043522B1 patent drawing
  • EP4043522B1 patent drawing

AI summary

Provided is a composition comprising a fluorine-containing polymer and a silicon oxide represented by formula: SiOx, where 0 &lt; x &lt; 2.