Fuel Cell Collector Structure for Gas Diffusion and Low Contact Resistance

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Solution Overview

Problem

Existing cell units face challenges in achieving both good gas diffusibility and electron conductivity due to increased contact resistance between the separator and auxiliary collector layer, which can be exacerbated by attempts to optimize either gas flow or electron conductivity, leading to insufficient performance in fuel cell stacks.

Innovation Solution

A cell unit design featuring a metal support cell assembly, an auxiliary collector layer with curved portions overlapping gas flow passages defined by a separator with convex/concave shapes, and a connecting portion that regulates relative displacement between the auxiliary collector layer and separator, ensuring balanced surface pressure and improved electron conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the auxiliary collector layer is embedded in the electrode to reduce contact resistance, then electron conductivity is improved, but gas diffusibility deteriorates

Engineering Contradiction:
Improveelectron conductivityVSAvoidgas diffusibility
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The auxiliary collector layer is divided into multiple independent protruding portions that contact the separator at discrete points, rather than forming a continuous embedded layer. This segmentation allows gas to diffuse through the spaces between protrusions while maintaining electrical contact points with the separator.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The auxiliary collector layer transitions from a two-dimensional embedded plane within the electrode to a three-dimensional structure with protrusions extending toward the separator. This dimensional change enables simultaneous achievement of electrical contact (at protrusion tips) and gas diffusion (through the volume between protrusions).

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Reliability

If the contact surface between separator and auxiliary collector layer is increased to reduce contact resistance, then electron conductivity is improved, but gas flow passage area decreases

Engineering Contradiction:
Improveelectron conductivityVSAvoidgas flow passage area
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The auxiliary collector layer exhibits spatially varying properties: protruding portions with high electron conductivity contact the separator to reduce contact resistance, while the regions between protrusions maintain gas permeability for diffusion. This local differentiation resolves the contradiction between contact area and flow area.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The auxiliary collector layer utilizes a porous or mesh-like structure that allows gas to pass through while maintaining electrical conductivity. The porous architecture provides both contact points for electron transfer and pathways for gas diffusion simultaneously.

Inventive Principle:
Principle #31Porous materials

3Reliability

If the auxiliary collector layer is positioned closer to the separator to reduce contact resistance, then electron conductivity is improved, but gas diffusion path is blocked

Engineering Contradiction:
Improveelectron conductivityVSAvoidgas diffusion path
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The protruding portions of the auxiliary collector layer have curved or rounded tips that contact the separator, rather than flat surfaces. This curvature allows point contact for electrical conduction while leaving the surrounding regions open for gas diffusion paths.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The design effectively reduces contact resistance while maintaining good gas diffusibility, enhancing the overall power generation performance by ensuring symmetrical surface pressure distribution and stable electrical contact.

Implementation Method 1

an auxiliary collector layer 130 that assists electrical contact between the power generation cell 111 and the separator 120

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

a separator 120 provided with flow passage portions 121 that define gas flow passages F for a gas

Methodology Applied
Scientific EffectGas diffusion: Diffusion

Implementation Method 3

load is concentrated at the portion where the power generation cell 111 and the portion of the curved portion 131 of the auxiliary collector layer 130 protruding toward the power generation cell 111 abut each other

Methodology Applied
Scientific EffectPressure concentration: Pressure Increase

Data Source

PatentEP3748751B1Cell unit
Publication Date: 2023.12.06 NISSAN MOTOR CO LTD
  • EP3748751B1 patent drawingFigure 1
  • EP3748751B1 patent drawingFigure 2
  • EP3748751B1 patent drawingFigure 3~4

AI summary

[PROBLEM] To provide a cell unit that can attain both good gas diffusibility and good electron conductivity. [SOLUTION] A cell unit 100 is made by sequentially stacking a power generation cell 111 including a cathode layer 111C, an electrolyte layer 111E, and an anode layer 111A, an auxiliary collector layer 130 that assists electrical contact, and a separator 120 provided with a flow passage portion 121 that defines a gas flow passage F. The auxiliary collector layer has a curved portion 131 that is disposed so as to overlap the gas flow passage F in the stacking direction, and that is curved so as to project toward the power generation cell side.