Encapsulating Fugitive Extracts in Porous Silica Particles

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Solution Overview

Problem

Supercritical fluid extraction methods face challenges in retaining and stabilizing fugitive extracts, such as flavors and aromas, due to their volatility and susceptibility to oxidation, leading to degradation during post-extraction processing and storage.

Innovation Solution

A process involving supercritical fluid extraction followed by deposition of the extracts within porous silica particles, where the extraction fluid is separated, and the extracts are trapped within the pores, with optional coatings on the particle surface to enhance stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If supercritical fluid extraction is used to extract fugitive extracts, then extraction efficiency is improved, but retention and stability of the extract deteriorate due to volatility and oxidation during post-extraction processing and storage

Engineering Contradiction:
Improveextraction efficiencyVSAvoidretention and stability of extract
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent applies preliminary action by directly depositing the extract into porous particles within the extraction vessel during the supercritical fluid extraction process itself, rather than performing separate post-extraction processing steps. This preliminary encapsulation prevents subsequent degradation during storage and handling.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes porous particles as a matrix to trap and retain the fugitive extract. The porous structure provides extensive surface area and confined spaces that physically immobilize the extract, preventing volatility and oxidation while maintaining the extract's functional properties.

Inventive Principle:
Principle #31Porous materials

2Reliability

If post-extraction processing steps are performed to recover the extract, then separation from extraction fluid is achieved, but degradation of the extract occurs due to handling and storage time

Engineering Contradiction:
Improveseparation completenessVSAvoidprocessing and storage time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent merges the extraction and separation operations into a single integrated process. The extract is deposited directly onto porous particles within the extraction vessel, and the supercritical fluid is then removed, achieving both extraction and separation simultaneously without intermediate handling steps that cause degradation.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The extract is preliminarily captured and stabilized on the porous particles before any separation or processing steps are performed. This preliminary encapsulation ensures the extract is protected from degradation mechanisms during subsequent processing and storage operations.

Inventive Principle:
Principle #10Preliminary action

3Ease of operation

If the extract is stored in liquid or concentrated form, then availability for use is improved, but susceptibility to oxidation and evaporation increases

Engineering Contradiction:
Improveavailability for useVSAvoidoxidation and evaporation
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The porous particles provide a solid matrix with high surface area that physically traps the extract molecules. This solid support form maintains ease of operation and availability while dramatically reducing susceptibility to oxidation and evaporation compared to liquid or concentrated forms.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent creates a composite material system consisting of the extract loaded onto porous particles. This composite form combines the functional properties of the extract with the stabilizing characteristics of the porous matrix, providing both availability and protection from harmful factors.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method improves the retention and integrity of fugitive extracts, eliminating the need for intermediary processing steps and extending the shelf-life of the final product while maintaining the functional properties of the extracts.

Implementation Method 1

performing a supercritical fluid extraction of a plant material or an animal material using an extration fluid to provide a mixture of the extraction fluid and the extract

Methodology Applied
Scientific EffectSupercritical fluid extraction: Supercritical Fluid Extraction

Implementation Method 2

the porous silica particles having pores of a size which permits diffusion of the mixture of extraction fluid and extract into the porous silica particles

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

reducing the pressure or changing the pressure and temperature of the extraction fluid so that extract deposits within the pores of the porous silica particles

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 4

contacting the mixture of the extraction fluid and the extract with a contained volume of porous silica particles... so that extract deposits within the pores

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP2699114B1Encapsulation of extract in porous particles
Publication Date: 2018.06.06 PEPSICO INC
  • EP2699114B1 patent drawingFigure 1
  • EP2699114B1 patent drawingFigure 2
  • EP2699114B1 patent drawingFigure 3

AI summary

A process in which the extract of an extraction process, such as a supercritical fluid extraction process, such as a fugitive extract and particularly an ingestible extract, is recovered by depositing the extract within the pores of a porous particle that is suitable for direct use as a food additive, or as a nutraceutical.