Gate Electrode Crystal Orientation for Low-Resistance Memory Devices

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Solution Overview

Problem

Current semiconductor devices, such as scaled-down MOSFETs and three-dimensional NAND flash memories, face challenges in achieving low-resistance gate electrode layers to suppress gate delay and enhance speed, as existing materials and structures do not effectively orient crystal axes for optimal crystallinity and reduced electrical resistance.

Innovation Solution

The semiconductor device incorporates a gate electrode layer with a first conductive layer and a second conductive layer, both having their crystal axes oriented within specific ranges relative to the semiconductor layer, and an aluminum oxide insulating layer with specific crystal phases, enhancing crystallinity and reducing electrical resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional gate electrode layer structures are used, then manufacturing is simpler, but electrical resistance is high and gate delay increases

Engineering Contradiction:
Improvegate delayVSAvoidcrystal axis orientation
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the physical and chemical parameters of the gate electrode layer by controlling crystal axis orientation within specific angular ranges (±10° or ±15°) and selecting specific crystal phases (α-aluminum oxide, θ-aluminum oxide) in the insulating layer to achieve low electrical resistance and suppressed gate delay

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material structures including multiple conductive layers (first conductive layer with first material, second conductive layer with second material) and insulating layers with specific crystal phases, where the combination and orientation of these materials work together to reduce electrical resistance while maintaining manufacturability

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If crystal axis orientation is not controlled, then manufacturing is easier, but crystallinity is poor and electrical resistance increases

Engineering Contradiction:
ImprovecrystallinityVSAvoidcrystal axis control process
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent specifies precise parameter ranges for crystal axis orientation (±10° or ±15° relative to the thickness direction) and crystal phase composition to achieve optimal crystallinity, balancing manufacturing precision requirements with ease of manufacture

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The insulating layer containing aluminum oxide with specific crystal phases (α-aluminum oxide, θ-aluminum oxide) acts as an intermediary that promotes and maintains the crystal axis orientation of the underlying conductive layers, facilitating crystallinity improvement without requiring direct complex control of each layer

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If standard insulating layers are used, then device structure is simpler, but leakage current is not minimized

Engineering Contradiction:
Improveleakage currentVSAvoidinsulating layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the insulating layer structure by incorporating aluminum oxide with specific crystal phases (α-aluminum oxide, θ-aluminum oxide) and controlling the thickness (5-20 nm) to minimize leakage current, while maintaining a relatively simple overall device structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality improvement by using aluminum oxide with specific crystal phases in the insulating layer at critical interfaces, where the local crystal structure and composition are optimized to minimize leakage current without requiring complex modifications throughout the entire device

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration improves the crystallinity of the metal and barrier metal layers, reduces electrical resistance, and minimizes leakage current, thereby enhancing the performance and efficiency of the semiconductor device.

Implementation Method 1

the aluminum oxide including at least one crystal phase selected from a group consisting of α (alpha)-aluminum oxide and θ (theta)-aluminum oxide. The direction of the crystal axis of the aluminum oxide in the first insulating layer falls within a range of ±10° with respect to a first direction from the semiconductor layer toward the gate electrode layer

Methodology Applied
Scientific EffectCrystallisation: Crystallisation

Implementation Method 2

both having their crystal axes oriented within specific ranges relative to the semiconductor layer, and an aluminum oxide insulating layer with specific crystal phases, enhancing crystallinity and reducing electrical resistance

Methodology Applied
Scientific EffectElectrical Resistance: Electrical Resistance

Data Source

PatentUS20240258401A1Semiconductor device and semiconductor memory device
Publication Date: 2024.08.01 KIOXIA CORP
  • US20240258401A1 patent drawing
  • US20240258401A1 patent drawing
  • US20240258401A1 patent drawing

AI summary

A semiconductor device of embodiments includes: a semiconductor layer; a gate electrode layer including a first conductive layer containing a first material and a second conductive layer between the first conductive layer and the semiconductor layer and containing a second material different from the first material; and a first insulating layer between the semiconductor layer and the gate electrode layer and containing aluminum oxide, the aluminum oxide including α (alpha)-aluminum oxide or θ (theta)-aluminum oxide. The direction of the crystal axis of the aluminum oxide falls within a range of ±10° with respect to a first direction from the semiconductor layer toward the gate electrode layer. The direction of the crystal axis of the first material falls within a range of ±10° with respect to the first direction. The direction of the crystal axis of the second material falls within a range of ±10° with respect to the first direction.