Graphene Resistance Regulation via Metal-Mediated Electron Beam Patterning

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Solution Overview

Problem

Existing methods for patterning graphene, carbon nanotubes, fullerene, or graphite often result in physical or chemical damage, altering their electrical characteristics, necessitating improved manufacturing techniques for regulating resistance.

Innovation Solution

A method involving the deposition of metal-containing materials like Al, Ni, Fe, Co, Ti, or Cr, followed by electron beam irradiation on specific areas to create structures with position-specific regulated resistance, allowing for controlled electrical properties without damaging the materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional patterning methods (etching by AFM, TEM, FIB, or photolithography) are used to form fine structures, then fine structures can be created, but the structures suffer from physical or chemical damage and altered characteristics

Engineering Contradiction:
Improvefine structure formationVSAvoidstructural integrity and electrical characteristics
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

A metal-containing material layer is introduced as an intermediary between the electron beam and the carbon material. This intermediary layer absorbs the electron beam's energy and facilitates localized structural transformation without directly damaging the carbon material, thereby enabling fine structure formation while preserving structural integrity and electrical characteristics

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces conventional mechanical etching methods (AFM, FIB) and chemical etching (photolithography) with an electron beam-based method. This substitution eliminates the physical contact and chemical reagents that cause damage, using instead electron beam energy mediated by the metal-containing material to achieve precise structural modification

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If no metal-containing material is deposited, then the inherent characteristics of graphene, carbon nanotubes, fullerene, or graphite are preserved, but position-specific resistance regulation cannot be achieved

Engineering Contradiction:
Improveinherent material characteristicsVSAvoidposition-specific resistance regulation
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The metal-containing material is deposited in a position-specific manner on the carbon material surface. This localized deposition enables different regions to have different properties: areas with metal-containing material exhibit regulated resistance, while areas without it maintain inherent characteristics, achieving both preservation and adaptability

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The metal-containing material layer undergoes electron beam irradiation to transform from a non-conductive or low-conductivity state to a conductive state with regulated resistance. This parameter change (electrical conductivity) is localized to specific positions, enabling position-specific resistance regulation while the rest of the material retains its inherent properties

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method efficiently manufactures graphene, carbon nanotubes, fullerene, or graphite with position-specific regulated resistance, enabling their use in advanced electronic devices like transistors without altering their inherent characteristics.

Implementation Method 1

irradiating an electron beam on one or more specific areas of the structure

Methodology Applied
Scientific EffectElectron beam irradiation: Electron Beam

Implementation Method 2

depositing a metal-containing material onto the graphene, carbon nanotubes, fullerene, graphite, or combination thereof

Methodology Applied
Scientific EffectMaterial deposition: Deposition (physical)

Data Source

PatentUS9122165B2Method of manufacturing graphene, carbon nanotubes, fullerene, graphite or a combination thereof having a position specifically regulated resistance
Publication Date: 2015.09.01 SAMSUNG ELECTRONICS CO LTD
  • US9122165B2 patent drawing
  • US9122165B2 patent drawing
  • US9122165B2 patent drawing

AI summary

Provided are a method of manufacturing graphene, carbon nanotubes, fullerene, graphite, or a combination thereof having a regulated resistance, and a material manufactured using the method.