Green-Absorbing Semiconductor Composition for Small-Pixel Image Sensors

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Solution Overview

Problem

Silicon photodiodes in image sensors suffer from reduced sensitivity due to small absorption areas, leading to deteriorated performance in light conversion and high integration capabilities.

Innovation Solution

A composition for a photoelectric device using a p-type semiconductor compound represented by Chemical Formula 1 and an n-type semiconductor compound, which selectively absorbs light in the green wavelength region, enhancing sensitivity and thermal stability, and potentially replacing silicon photodiodes in image sensors.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If silicon photodiodes are used in image sensors to achieve high resolution, then pixel size can be reduced, but sensitivity deteriorates due to small absorption area

Engineering Contradiction:
ImproveresolutionVSAvoidsensitivity
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent changes the material parameter from silicon to organic semiconductor compounds with specific molecular structures (Formula 1 and Formula 2) that have high extinction coefficients and strong light absorption capability in the green wavelength region, enabling small pixels to maintain high sensitivity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite approach by combining p-type semiconductor compound (Formula 1) and n-type semiconductor compound (Formula 2) in specific ratios to create an organic photodiode material that achieves both high sensitivity and stability, replacing traditional silicon photodiodes

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If organic semiconductor compounds are used to replace silicon photodiodes, then light absorption efficiency improves, but thermal stability may deteriorate under high-temperature conditions

Engineering Contradiction:
Improvelight absorption efficiencyVSAvoidthermal stability
Core Design Contradiction:
Use of energy by moving objectVSStability of the object's composition

Solution Approach 1:

The patent optimizes the molecular structure parameters of organic semiconductor compounds (Formula 1 and Formula 2) with specific functional groups and conjugated structures that provide both high light absorption efficiency in the green wavelength region and enhanced thermal stability for high-temperature process compatibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces specific functional groups and molecular structures at local positions within the organic semiconductor compounds to simultaneously achieve high extinction coefficient for light absorption and thermal stability, with p-type and n-type compounds having complementary local structural features

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition improves light absorption efficiency and sensitivity in the green wavelength region, maintaining performance even under high-temperature conditions, and enables high integration without degrading device efficiency.

Implementation Method 1

A photoelectric device may convert light into an electrical signal using photoelectric effects

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Data Source

PatentUS12448397B2Composition for photoelectric device, and photoelectric device, image sensor and electronic device including the same
Publication Date: 2025.10.21 SAMSUNG ELECTRONICS CO LTD
  • US12448397B2 patent drawing
  • US12448397B2 patent drawing
  • US12448397B2 patent drawing

AI summary

A composition for a photoelectric device includes a compound represented by Chemical Formula 1, and an image sensor and an electronic device including the same:In Chemical Formula 1, each substituent is the same as defined in the detailed description.