Halogenated Poly(Melamine-Silicate) Biocides With Metal Oxides

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Solution Overview

Problem

There is an urgent need for novel biocidal materials that can efficiently and safely neutralize pathogens such as viruses, bacteria, fungi, protozoa, algae, parasites, and toxic organic agents, while addressing issues of resistance and safety, particularly in healthcare and environmental applications.

Innovation Solution

The development of halogenated adducts of poly(melamine-silicate) with metal oxides, which are prepared by complexing metal oxides with melamine-silicate either before or after polymerization and then halogenating, creating a hybrid biocide with synergistic antimicrobial and oxidizing properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional biocides are used for disinfection, then pathogen neutralization is achieved, but resistance development and safety issues arise

Engineering Contradiction:
Improvepathogen neutralization effectivenessVSAvoidresistance and safety issues
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent combines multiple biocidal mechanisms into a single composite material: poly(melamine-silicate) provides structural framework and binding capacity, metal oxides (such as zinc oxide, magnesium oxide, calcium oxide) contribute antimicrobial properties, and halogenation (chlorine, bromine, iodine) adds oxidizing biocidal activity. This multi-component composite approach creates synergistic effects that enhance pathogen neutralization while reducing resistance development compared to single biocides.

Inventive Principle:
Principle #40Composite materials

2Productivity

If existing biocidal materials are employed, then disinfection is achieved, but safety risks including cancer and immune disorders increase

Engineering Contradiction:
Improvedisinfection capabilityVSAvoidmedical risks including cancer or immune disorders
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the chemical parameters of traditional biocides by incorporating metal oxides with specific properties (zinc oxide, magnesium oxide, calcium oxide) that have low toxicity and high safety profiles. The halogenation level is controlled to achieve optimal biocidal activity while minimizing harmful byproducts. The poly(melamine-silicate) structure provides controlled release of active components, reducing acute toxicity risks associated with conventional biocides.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If novel biocidal structures are developed, then resistance and safety are improved, but manufacturing complexity increases

Engineering Contradiction:
Improveresistance and safety profileVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent divides the biocidal material into distinct functional segments that can be manufactured separately and then combined: the poly(melamine-silicate) polymer matrix is synthesized first, then metal oxide nanoparticles are incorporated, and finally halogenation is applied. This segmented manufacturing approach allows each component to be optimized and produced using established processes, reducing overall manufacturing complexity despite the advanced composite structure.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting biocidal materials effectively neutralize a wide range of pathogens, including antibiotic-resistant bacteria, and can be used in various applications like water and air purification, medical textiles, and skin protection, with the potential for regenerating N-halogen bonds for repeated use.

Implementation Method 1

N-halamines have been broadly used as disinfectants in water purification systems and other applications, while employing relative stability of the active halogen bound to nitrogen during storage and its easy release in contact with oxidizable contaminants

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

comprising steps i) complexing a metal oxide with a melamine-silicate either before or after polymerizing said melamine silicate, and ii) halogenating said melamine-silicate metal complex

Methodology Applied
Scientific EffectComplexing:

Data Source

PatentUS20250339578A1Poly(melamine-silicate) derivatives as biocidal agents for disinfection and decontamination
Publication Date: 2025.11.06 STATE OF ISRAEL REPRESENTED BY THE PRIME MINISTER'S OFFICE ISRAEL INSTITUTE FOR BIOLOGICAL RESEARCH
  • US20250339578A1 patent drawing
  • US20250339578A1 patent drawing
  • US20250339578A1 patent drawing

AI summary

The present subject matter relates to poly(melamine-silicate) derivatives as biocidal disinfection and decontamination agents, and to methods for their production and use. More specifically, the subject matter relates to halogenated adducts of poly(melamine-silicate) with metal oxides.