Hardmask Tuning via Electrode Capacitance Adjustment

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Solution Overview

Problem

Conventional semiconductor processing methods face challenges in producing high-quality, carbon-rich films with improved etch selectivity and film density, often resulting in thicker hardmask films that can cause damage and porosity issues during subsequent processing operations.

Innovation Solution

The method involves forming a plasma of a carbon-containing precursor in a semiconductor processing chamber, adjusting a variable capacitor within 20% of its resonance peak to increase capacitance, and using an electrostatic chuck with a DC power supply to deposit a carbon-containing material with greater than 67% carbon content, achieving etch selectivity greater than 2:1 relative to silicon oxide.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional deposition methods are used to produce carbon-containing films, then film thickness can be increased to improve etch selectivity, but film porosity and damage increase, reducing film quality

Engineering Contradiction:
Improveetch selectivityVSAvoidfilm quality
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies parameter changes by adjusting the capacitance of the variable capacitor to operate within 20% of the resonance peak, and setting the DC power supply to specific voltage ranges (200-400V). These parameter adjustments optimize the plasma deposition process to produce films with sufficient etch selectivity (greater than 2:1) while maintaining film density and reducing porosity, thus resolving the contradiction between etch selectivity and film quality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes phase transitions by controlling the deposition process to achieve proper film densification. By optimizing the plasma parameters through capacitance adjustment near resonance peak and controlling deposition conditions, the carbon-containing films transition from porous to dense structures, achieving both high etch selectivity and film quality simultaneously

Inventive Principle:
Principle #36Phase transitions

2Quantity of substance

If capacitance of variable capacitor is increased within 20% of resonance peak, then carbon content and film density increase, but process complexity increases

Engineering Contradiction:
Improvecarbon contentVSAvoidprocess complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent applies universality by using the variable capacitor to serve multiple functions: it acts as both a plasma generation component and a capacitance tuning device to control carbon content. By integrating these functions into a single component and optimizing its operation within 20% of resonance peak, the system achieves high carbon content films without proportionally increasing process complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent uses parameter changes by establishing specific operating ranges for the variable capacitor (within 20% of resonance peak) and DC power supply (200-400V). These defined parameter ranges simplify the control process while achieving the desired carbon content (greater than 67 at.%) and film density, reducing the complexity of process optimization

Inventive Principle:
Principle #35Parameter changes

3Productivity

If DC power supply voltage is increased to operate electrostatic chuck, then material deposition efficiency improves, but energy consumption increases

Engineering Contradiction:
Improvedeposition efficiencyVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by stationary object

Solution Approach 1:

The patent applies parameter changes by optimizing the DC power supply voltage to specific ranges (200-400V) that balance deposition efficiency and energy consumption. This optimized voltage range provides sufficient electrostatic chucking force and deposition rate while avoiding excessive energy use, resolving the contradiction between productivity and energy consumption

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach produces carbon-containing films with increased carbon content and density, enhancing etch selectivity and maintaining film quality, allowing for thinner hardmasks with improved operational performance.

Implementation Method 1

adjusting a variable capacitor within 20% of a resonance peak. The variable capacitor may be coupled with an electrode incorporated within a substrate support

Methodology Applied
Scientific EffectCapacitance: Capacitance

Implementation Method 2

adjusting a variable capacitor within 20% of a resonance peak

Methodology Applied
Scientific EffectResonance: Resonance

Implementation Method 3

The electrode incorporated within the substrate support may also be coupled with a DC power supply to operate as an electrostatic chuck

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Implementation Method 4

forming a plasma of a carbon-containing precursor in a processing region of a semiconductor processing chamber

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 5

depositing a carbon-containing material on the substrate

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Data Source

PatentUS11515150B2Hardmask tuning by electrode adjustment
Publication Date: 2022.11.29 APPLIED MATERIALS INC
  • US11515150B2 patent drawing
  • US11515150B2 patent drawing
  • US11515150B2 patent drawing

AI summary

Exemplary processing methods may include forming a plasma of a deposition precursor in a processing region of a semiconductor processing chamber. The methods may include adjusting a variable capacitor within 20% of a resonance peak. The variable capacitor may be coupled with an electrode incorporated within a substrate support on which a substrate is seated. The methods may include depositing a material on the substrate.