HDP-CVD Silicon Nitride Film Stress Control for OLED Encapsulation

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Solution Overview

Problem

Conventional encapsulation layers in OLED devices fail to effectively prevent moisture and oxygen ingress, leading to degradation and reduced lifetimes due to compressive film stress in silicon nitride barrier layers deposited using conventional HDP-CVD processes.

Innovation Solution

A method involving high density plasma chemical vapor deposition (HDP-CVD) with controlled biasing of the substrate during silicon nitride deposition to achieve low film stress and compressive stress, resulting in superior barrier properties by depositing silicon nitride layers with tunable tensile or compressive stress.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional HDP-CVD process is used to deposit silicon nitride barrier layers, then the barrier layers provide encapsulation for OLED devices, but compressive film stress causes degradation and reduces device lifetime

Engineering Contradiction:
Improvedevice lifetimeVSAvoidcompressive film stress
Core Design Contradiction:
ReliabilityVSStress or pressure

Solution Approach 1:

The patent applies parameter changes by modifying the deposition conditions in HDP-CVD process, specifically changing the substrate bias voltage from conventional values to a specific range (-100V to -300V), and adjusting the ratio of silane to ammonia flow rates. These parameter modifications transform the film stress from compressive to tensile, resolving the contradiction between providing barrier function and avoiding stress-induced degradation.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If existing encapsulation layers are used, then they provide basic protection against moisture and oxygen ingress, but they fail to prevent failure of OLED devices over time

Engineering Contradiction:
Improvemoisture and oxygen ingressVSAvoiddevice stability over time
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent modifies the deposition parameters to achieve tensile stress in the silicon nitride barrier layers, which fundamentally changes the mechanical properties of the encapsulation structure. This parameter change enables the barrier layers to better resist moisture and oxygen ingress over time, preventing the failure that occurs with conventional encapsulation layers.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enhances the barrier properties of silicon nitride layers, preventing moisture and oxygen ingress, thereby improving the longevity of OLED devices by maintaining stability and reducing cracks in the encapsulation structure.

Implementation Method 1

depositing a silicon nitride layer on the substrate... using high density plasma chemical vapor deposition (HDP-CVD)

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

forming a high density plasma of the precursor gases

Methodology Applied
Scientific EffectPlasma: Plasma

Data Source

PatentUS10312475B2CVD thin film stress control method for display application
Publication Date: 2019.06.04 APPLIED MATERIALS INC
  • US10312475B2 patent drawing
  • US10312475B2 patent drawing
  • US10312475B2 patent drawing

AI summary

Embodiments of the present disclosure generally describe a method for depositing a barrier layer of SiN using a high density plasma chemical vapor deposition (HDP-CVD) process, and in particular, controlling a film stress of the deposited SiN layer by biasing the substrate during the deposition process.