Horizontal Gate-All-Around Oxide Formation Using Plasma Oxidation

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Solution Overview

Problem

Conventional I/O oxide processes for forming horizontal gate-all-around devices result in poor quality native oxide, low-density oxide deposition, and increased complexity and cost due to the need for additional post-treatment to densify the ALD film.

Innovation Solution

The method involves pre-cleaning a plurality of nanosheet channel layers, forming a conformal sacrificial epitaxial layer, and then oxidizing this layer using plasma to form a high-quality silicon oxide layer on the nanosheets, thereby improving the electrostatic coupling and reducing parasitic capacitance and off-state leakage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional I/O oxide processes are used, then oxide deposition is achieved, but the oxide quality is poor and density is low

Engineering Contradiction:
Improveoxide qualityVSAvoidoxide density
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by performing a pre-clean step on the nanosheet channel layers before oxide deposition. This pre-clean removes contaminants and prepares the surface, enabling subsequent formation of high-quality, high-density oxide without requiring post-treatment densification steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the oxidation method parameter from conventional ALD (Atomic Layer Deposition) to plasma oxidation. This parameter change transforms the oxidation process to produce high-density oxide directly, eliminating the need for post-deposition densification while achieving superior oxide quality.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If ALD oxide deposition is used, then oxide layer is formed, but additional post treatment is required to densify the film

Engineering Contradiction:
Improveoxide densityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent extracts and removes the post-treatment densification step from the conventional ALD oxide formation process. By using plasma oxidation instead of ALD, the method directly produces dense oxide without requiring the additional post-treatment step, thereby simplifying the overall process.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the deposition method from ALD to plasma oxidation. This parameter change fundamentally alters the deposition mechanism to produce dense oxide in-situ, eliminating the need for subsequent densification treatments and reducing process complexity.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional oxide formation is used, then oxide layer is deposited, but electrostatic control is poor and parasitic capacitance increases

Engineering Contradiction:
Improveelectrostatic controlVSAvoidparasitic capacitance
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies preliminary action by pre-cleaning the nanosheet surfaces before oxide formation. This ensures a clean interface that enables optimal electrostatic coupling between the gate and channel, reducing parasitic capacitance and improving electrostatic control of the device.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the oxide formation method to plasma oxidation, which produces high-quality oxide with superior dielectric properties. This parameter change improves electrostatic control by reducing interface states and minimizing parasitic capacitance, leading to better device performance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the formation of high-quality I/O oxides with improved electrostatic control, reducing negative effects such as parasitic capacitance and off-state leakage, while also simplifying the manufacturing process and reducing costs.

Implementation Method 1

oxidizing the conformal sacrificial epitaxial silicon layer using a plasma to form a silicon oxide layer on the nanosheet

Methodology Applied
Scientific EffectPlasma oxidation: Oxidation

Data Source

PatentUS20250203942A1Formation Of Gate All Around Device
Publication Date: 2025.06.19 APPLIED MATERIALS INC
  • US20250203942A1 patent drawing
  • US20250203942A1 patent drawing
  • US20250203942A1 patent drawing

AI summary

Horizontal gate-all-around devices and methods of manufacturing same are described. The hGAA devices comprise an oxide layer and a semiconductor material layer between source regions and drain regions of the device. The method includes growing a conformal epitaxial layer on a nanosheet channel layer, followed by radical plasma oxidation (RPO) to oxidize the conformal epitaxial layer. An alternative method includes growing a conformal epitaxial layer on a nanosheet channel layer, followed by a surface treatment, and then radical plasma oxidation (RPO) to oxidize the conformal epitaxial layer.