High-k Gate Dielectric Crystallization for Uniform Grain Size

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Solution Overview

Problem

As semiconductor devices continue to shrink in size, challenges arise in maintaining process stability and achieving uniform grain size control in gate dielectric layers, which affects the integration density and performance of electronic components.

Innovation Solution

The formation of a template layer to control the grain size of gate dielectric layers, combined with a crystallization process such as soak or spike anneal, ensures uniformity and stability, using high-k gate dielectric layers with sub-nm grain sizes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If minimum feature size is reduced to improve integration density, then more components can be integrated into a given area, but process stability and grain size uniformity deteriorate

Engineering Contradiction:
Improveintegration densityVSAvoidprocess stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

A template layer is formed prior to depositing the gate dielectric layer to pre-establish a grain structure framework. This preliminary action enables subsequent gate dielectric deposition to follow the template's grain patterns, ensuring uniform grain size even as feature dimensions are reduced for higher integration density.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent employs crystallization processes (soak anneal or spike anneal) to change the physical state and grain structure parameters of the gate dielectric layer. By controlling annealing temperature and duration, uniform sub-10nm grain sizes are achieved, maintaining process stability despite continued scaling of minimum feature sizes.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If minimum feature size is reduced to improve integration density, then more components can be integrated into a given area, but grain size uniformity deteriorates

Engineering Contradiction:
Improveintegration densityVSAvoidgrain size uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The template layer is deposited and processed before the gate dielectric layer to pre-establish a grain size framework. This preliminary grain structure serves as a template that guides the formation of uniform grains in the subsequent gate dielectric, ensuring consistent grain size across the wafer even at reduced feature dimensions.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

Crystallization processes induce phase transitions in the gate dielectric material, transforming it from an amorphous or nanocrystalline state to a controlled crystalline structure with uniform grain sizes. The soak anneal or spike anneal processes facilitate this phase transition, achieving sub-10nm grain uniformity required for high-density integration.

Inventive Principle:
Principle #36Phase transitions

3Manufacturing precision

If template layer and crystallization process are used to control grain size and improve process stability, then manufacturing precision improves, but device complexity increases

Engineering Contradiction:
Improvegrain size controlVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The template layer acts as an intermediary between the substrate and the gate dielectric layer. It mediates the grain formation process by providing a pre-established grain structure that the gate dielectric follows during deposition and crystallization, simplifying the overall control of grain size despite the additional process step.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

By controlling the crystallization parameters (temperature, time, atmosphere) of the template layer and subsequent gate dielectric, the process achieves precise grain size control. The standardized annealing protocols (soak or spike) transform complex material science challenges into controllable process parameters, managing device complexity through parameter optimization.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances process stability and scalability, improving the integration density and performance of nano-FETs by controlling the grain size and crystalline phase of gate dielectric layers.

Implementation Method 1

the gate dielectric layer is a crystalline layer

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 2

crystallization process such as soak or spike anneal

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS12568662B2Semiconductor devices and methods of forming the same
Publication Date: 2026.03.03 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US12568662B2 patent drawing
  • US12568662B2 patent drawing
  • US12568662B2 patent drawing

AI summary

An embodiment includes a device including a first high-k gate dielectric on a first channel region of a first semiconductor feature, the first high-k gate dielectric being a crystalline layer with a grain size in a range of 10 Å to 200 Å. The device also includes a first gate electrode on the first high-k gate dielectric. The device also includes a source region and a drain region on opposite sides of the first gate electrode.