High-K Transistor Annealing with Negative Bias

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Solution Overview

Problem

High-k dielectrics on silicon-based channels in field effect transistors result in undesirably high threshold voltage due to the formation of oxygen vacancies during anneal, leading to increased gate leakage current and power consumption.

Innovation Solution

Applying a negative electrical bias to the gate electrode during an anneal process above 350°C to inhibit the formation of oxygen vacancies in high-k dielectric layers, thereby reducing the energy gain for electron transfer and decreasing the density of oxygen vacancies, which in turn reduces the threshold voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If high-k dielectric materials are used in gate stacks, then gate leakage current is reduced, but threshold voltage becomes too high

Engineering Contradiction:
Improvegate leakage currentVSAvoidthreshold voltage
Core Design Contradiction:
Loss of energyVSObject-generated harmful factors

Solution Approach 1:

The patent applies a negative electrical bias parameter during the annealing process to change the electrical state of the gate stack. This parameter change inhibits oxygen vacancy formation and reduces the positive charge density in the high-k dielectric, thereby adjusting the threshold voltage to an acceptable range while maintaining low gate leakage current

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The negative bias is applied during the annealing process before the device is fully operational. This preliminary action prevents the formation of oxygen vacancies and excessive positive charge accumulation in the high-k dielectric layer, ensuring optimal electrical characteristics are established before the transistor begins normal operation

Inventive Principle:
Principle #10Preliminary action

2Reliability

If anneal temperature is increased above 350°C, then oxygen vacancy formation is inhibited, but process complexity increases

Engineering Contradiction:
Improveoxygen vacancy densityVSAvoidanneal process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent introduces an electrical bias parameter to the annealing process, transforming it from a purely thermal process to a combined thermal-electrical process. This additional parameter enables better control over oxygen vacancy formation, improving reliability while the increased temperature provides the thermal energy needed for effective vacancy suppression

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively reduces the density of oxygen vacancies and the resulting positive charge in high-k dielectric layers, leading to a less negative threshold voltage and improved performance in p-channel FETs by minimizing gate leakage current and power consumption.

Implementation Method 1

a negative electrical bias is formed across one or more gate stacks of the wafer

Methodology Applied
Scientific EffectElectrical bias: Electric Field

Implementation Method 2

when the wafer is annealed

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 3

decreasing the density of oxygen vacancies

Methodology Applied
Scientific EffectElectron transfer: Electron Beam

Data Source

PatentUS8674456B2High-K transistors with low threshold voltage
Publication Date: 2014.03.18 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US8674456B2 patent drawing
  • US8674456B2 patent drawing
  • US8674456B2 patent drawing

AI summary

An apparatus includes a wafer annealing tool and a plurality of electrodes coupled to the wafer annealing tool, wherein the electrodes are configured to be in physical contact with a wafer so that, when the wafer is annealed, a negative electrical bias is formed across one or more gate stacks of the wafer.