High Styrene Tire Tread Resolving Grip Abrasion Trade-off

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Solution Overview

Problem

High-performance tires face challenges in balancing grip and durability due to the limitations of traditional styrene-butadiene copolymers, which struggle to maintain mechanical properties and abrasion resistance at high temperatures, especially when used at high speeds and on curves.

Innovation Solution

Incorporating a stereoregular styrene-butadiene copolymer with a styrene content higher than 40% by weight, in a random iso-styrene/trans-butadiene configuration, into the elastomeric composition to enhance crosslinking and hysteresis, while maintaining low molecular weight and specific molecular weight distribution, improves the tire's resistance to tearing and grip.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If traditional styrene-butadiene copolymers with high styrene content are used to increase grip and hysteresis, then grip is improved, but block copolymer formation occurs which compromises mechanical properties and abrasion resistance

Engineering Contradiction:
ImprovegripVSAvoidabrasion resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the molecular weight parameter of the styrene-butadiene copolymer to below 500,000 and controls the styrene content to be between 40-90 wt.%, preventing block copolymer formation while maintaining high hysteresis and grip. This parameter optimization resolves the contradiction between grip improvement and abrasion resistance maintenance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite elastomeric composition combining low molecular weight styrene-butadiene copolymer with other elastomeric polymers, achieving synergistic effects that provide both high grip through increased hysteresis and maintained durability through controlled copolymer structure that prevents thermoplastic block formation.

Inventive Principle:
Principle #40Composite materials

2Reliability

If elastomeric compositions with Tg between -90°C and -40°C are used to achieve low rolling resistance and high abrasion resistance, then durability is improved, but grip is reduced

Engineering Contradiction:
Improveabrasion resistanceVSAvoidgrip
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent optimizes the glass transition temperature parameter to fall within -90°C to -40°C while simultaneously achieving high grip through the specific combination of low molecular weight copolymer and controlled styrene content, resolving the traditional trade-off between durability and grip.

Inventive Principle:
Principle #35Parameter changes

3Strength

If high percentages of styrene are added to increase hysteresis values and grip, then grip is improved, but the copolymer becomes thermoplastic and mechanical properties are compromised

Engineering Contradiction:
ImprovegripVSAvoidthermoplasticity
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent precisely controls the molecular weight parameter to below 500,000 and styrene content to 40-90 wt.%, which allows high hysteresis values and improved grip while preventing the formation of thermoplastic block copolymers. This maintains compositional stability and mechanical properties even at high styrene concentrations.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of this copolymer composition results in a tire tread with improved resistance to tearing, reduced thermoplasticity, and enhanced grip, maintaining performance consistency even at high temperatures, thus addressing the limitations of traditional materials.

Implementation Method 1

a crosslinked elastomeric material obtained by crosslinking a crosslinkable elastomeric composition comprising a polymer with a high styrene content

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

the use of polymers and/or copolymers with high styrene content makes it possible to increase the hysteresis values of the finished tyre tread

Methodology Applied
Scientific EffectHysteresis: Hysteresis

Data Source

PatentEP2643367B1High-performance tyre
Publication Date: 2015.02.11 PIRELLI TYRE SPA
  • EP2643367B1 patent drawingFigure 1
  • EP2643367B1 patent drawing
  • EP2643367B1 patent drawing

AI summary

The present invention relates to a tyre for wheels of vehicles, in particular cars, characterized by a tread comprising at least one polymer with a high styrene content. Said tread is characterized by improved characteristics of grip and/or resistance to tearing.