Hemispherical Grain DRAM Capacitor Depletion Ratio Reduction

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Solution Overview

Problem

Conventional semiconductor integrated circuit capacitors exhibit high depletion ratios due to variations in capacitance values when biased with positive and negative voltages, leading to reduced storage performance and frequent charge refresh requirements, especially in DRAM applications.

Innovation Solution

A method involving the formation of hemispherical grains on a polysilicon layer, followed by phosphorous doping in specific temperature and pressure conditions, and subsequent rapid thermal oxidation and nitridation processes to create a low depletion ratio capacitor, with an alumina film deposition to enhance surface area and reduce capacitance variation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional capacitor structures are used in DRAM, then manufacturing is simpler, but depletion ratio is high causing capacitance variation

Engineering Contradiction:
Improvecapacitance consistencyVSAvoidcapacitor structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies hemispherical grain structure to the polysilicon lower electrode, transforming the flat surface into a curved spherical surface. This curvature increases the effective surface area by approximately 39% compared to a flat surface, thereby increasing capacitance while maintaining the same footprint. The spherical geometry also promotes uniform electric field distribution, reducing depletion effects and improving capacitance consistency across positive and negative biases.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Solution Approach 2:

The patent implements a multi-layer nested structure where the hemispherical grain polysilicon lower electrode is nested within a trench, which is further nested within a dielectric layer containing an alumina film, which is then nested within an upper electrode structure. This nested arrangement maximizes the use of vertical space to increase effective capacitor surface area without increasing the planar footprint, thereby improving capacitance consistency without excessive complexity.

Inventive Principle:
Principle #7Nested doll (Nesting)

2Quantity of substance

If capacitor surface area is increased to improve charge storage, then charge storage capacity increases, but device footprint increases

Engineering Contradiction:
Improvecharge storage capacityVSAvoiddevice footprint
Core Design Contradiction:
Quantity of substanceVSArea of stationary object

Solution Approach 1:

The patent transitions from a two-dimensional planar capacitor structure to a three-dimensional hemispherical grain structure. By utilizing the vertical dimension and creating spherical grains within the polysilicon layer, the effective surface area is increased by approximately 39% without increasing the planar footprint. This dimensional transformation allows more charge storage capacity within the same device area.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The hemispherical grain structure creates a curved surface that packs more surface area into the same footprint compared to a flat surface. The spherical geometry naturally provides approximately 39% more surface area than a flat plane of the same footprint, enabling increased charge storage capacity without expanding the device area.

Inventive Principle:
Principle #14Spheroidality (Curvature)

3Reliability

If rapid thermal oxidation is applied to doped HSG polysilicon, then depletion ratio is reduced, but process complexity increases

Engineering Contradiction:
Improvedepletion ratioVSAvoidfabrication process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent performs phosphorous doping of the hemispherical grain polysilicon structure before applying rapid thermal oxidation. This preliminary doping action is crucial because it establishes the appropriate carrier concentration and electrical properties in the lower electrode before the oxidation process. The pre-doped structure then responds more favorably to the rapid thermal oxidation, achieving better depletion ratio reduction while managing process complexity through proper sequencing.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes rapid thermal oxidation to change the physical and chemical parameters of the doped polysilicon surface. The high-temperature oxidation process modifies the surface properties, reduces depletion effects, and improves capacitance consistency. By controlling oxidation time and temperature parameters, the process achieves reliable depletion ratio reduction while keeping the process complexity manageable through precise parameter control.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves a low depletion ratio of less than 10, improving capacitor performance by maintaining a consistent capacitance value across voltage biases, reducing leakage current, and enhancing breakdown voltage, while being compatible with conventional fabrication processes.

Implementation Method 1

doping the HSG formed polysilicon in a 200 Torr pressure gas atmosphere containing phosphine (PH3) at a temperature in the range of 600° C. to 700° C.

Methodology Applied
Scientific EffectPhosphorous doping: Dopants

Implementation Method 2

doping the HSG formed polysilicon in a 200 Torr pressure gas atmosphere containing phosphine (PH3) at a temperature in the range of 600° C. to 700° C.

Methodology Applied
Scientific EffectPhosphine decomposition: Thermolysis

Implementation Method 3

a rapid thermal oxidation process after phosphorous doping of a hemispherical grained poly-silicon film

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 4

nitridizing the doped HSG polysilicon

Methodology Applied
Scientific EffectNitridation: Nitriding

Implementation Method 5

an alumina film deposition to enhance surface area and reduce capacitance variation

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS8742542B2Method and device for a dram capacitor having low depletion ratio
Publication Date: 2014.06.03 SEMICON MFG INT (SHANGHAI) CORP
  • US8742542B2 patent drawing
  • US8742542B2 patent drawing
  • US8742542B2 patent drawing

AI summary

A method of manufacturing a semiconductor integrated circuit device having low depletion ratio capacitor comprising: forming hemispherical grains (HSG) on a poly-silicon; doping the hemispherical grained polysilicon in a phosphine gas; and rapid thermal oxidizing the doped hemispherical grained polysilicon at 850° C. for 10 seconds. The method further comprises nitridizing the rapid thermal oxidized hemispherical-grained polysilicon and depositing a alumina film on the silicon nitride layer. A semiconductor integrated circuit device having a low depletion ratio capacitor according to the disclosed manufacturing method is provided.