Hybrid Material Information Storage via Spin-Crossover Fluorescence

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing information storage methods face challenges such as mechanical damage, limited erasable times, high costs, complex processes, and low storage density, particularly due to their reliance on binary storage systems.

Innovation Solution

A method for information storage using a hybrid material that exhibits different fluorescent states or non-fluorescent states when subjected to external forces, allowing for ternary or binary storage by manipulating the energy band alignment between components A and B within the hybrid material.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional optical storage using laser ablation is used, then information can be stored, but mechanical damage occurs to the storage medium and equipment precision requirements increase

Engineering Contradiction:
Improvestorage medium integrityVSAvoidequipment precision
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent replaces the mechanical laser ablation system with a magnetic field-based storage system using spin-crossover materials. Instead of using high-precision optical equipment to ablate material, the invention uses magnetic fields to induce spin transitions that store information, thereby eliminating mechanical damage and reducing equipment precision requirements.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes spin-crossover phase transitions in coordination compounds as the storage mechanism. The material transitions between high-spin and low-spin states under magnetic field stimulation, providing a non-mechanical, reversible method for information storage that avoids damage to the storage medium.

Inventive Principle:
Principle #36Phase transitions

2Reliability

If conventional phase-transition memory devices using GeSbTe or GeTe are used, then storage function is achieved, but material preparation becomes complex and cost increases

Engineering Contradiction:
Improvestorage functionVSAvoidmaterial preparation complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs composite coordination compounds combining spin-crossover metal complexes with organic ligands. These composite materials integrate the magnetic response of metal centers with the structural stability of organic frameworks, achieving reliable storage function while simplifying preparation through solution-based synthesis methods compared to complex PVD/CVD processes.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the fundamental parameter for storage from phase transition temperature (in GeSbTe) to spin state magnetic response. This parameter change allows the use of coordination compounds that can be prepared by simpler chemical synthesis methods rather than requiring complex physical vapor deposition or chemical vapor deposition processes.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If conventional electronic memory chips are used, then information storage is achieved, but information is easily lost affecting service life

Engineering Contradiction:
Improveinformation storage capacityVSAvoidinformation retention
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent uses spin-crossover phase transitions that are thermally stable and reversible. The high-spin and low-spin states represent stable information states that can be maintained without power, providing non-volatile storage with long service life, unlike conventional electronic memory that requires continuous power to maintain data.

Inventive Principle:
Principle #36Phase transitions

4Quantity of substance

If conventional information storage methods are used, then binary storage (0 and 1) is achieved, but storage density becomes limited

Engineering Contradiction:
Improvestorage densityVSAvoidstorage cell structure
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent changes the storage mechanism from binary (0/1) to multi-state storage by utilizing different spin states (high-spin, intermediate-spin, low-spin) and different molecular aggregation states. This allows a single storage cell to represent multiple information states, increasing storage density without requiring more complex cell structures.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The spin-crossover material serves multiple functions: it provides the magnetic response for state switching, the structural framework for stable information retention, and the mechanism for multi-state representation. This multi-functionality enables high storage density while maintaining relatively simple cell structure.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables efficient information storage with improved storage density, reduced complexity and cost, and enhanced reliability, overcoming the limitations of conventional storage methods by achieving two or three storage states in a single cell.

Implementation Method 1

the hybrid material shows a fluorescent state or a non-fluorescent state, thereby realizing information storage

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 2

applying an external force to a hybrid material for driving, such that the hybrid material shows a fluorescent state or a non-fluorescent state

Methodology Applied
Scientific EffectPiezoluminescence: Piezoluminescence

Data Source

PatentUS12237012B2Method for information storage based on hybrid material
Publication Date: 2025.02.25 HPSTAR (BEIJING)
  • US12237012B2 patent drawing
  • US12237012B2 patent drawing
  • US12237012B2 patent drawing

AI summary

The present disclosure belongs to the technical field of information storage, and particularly relates to a method for information storage based on a hybrid material. The method for information storage based on a hybrid material provided by the present disclosure includes a step of applying an external force to a hybrid material for driving, such that the hybrid material shows a fluorescent state or a non-fluorescent state, thereby realizing two-state or three-state information storage. By only applying the external force to the selected hybrid material for driving, energy band alignment methods can be transformed under the driving of the external force with an energy level difference between different components in the hybrid material. Therefore, the hybrid material shows the component fluorescent state or the non-fluorescent state. One storage cell has two or three states, so the present disclosure can be used to store two-state or three-state data.