Metal Hydride-PCM Composite for Hydrogen Storage Heat Transfer

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Solution Overview

Problem

Current hydrogen storage systems based on metal hydrides face inefficiencies in heat transfer during hydrogen absorption and desorption, leading to complex and costly systems with ineffective use of phase changing materials (PCMs).

Innovation Solution

A composite material comprising encapsulated phase changing materials (EPCMs) homogeneously dispersed within metal hydride powders or pellets, which store and release heat to manage thermal energy, eliminating the need for separate vessels and piping by using encapsulated or microencapsulated PCMs with tailored melting temperatures matching the hydride's desorption and absorption temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by stationary object

If separate vessels and piping are used for phase changing materials (PCMs), then thermal energy storage is achieved, but system complexity and cost increase

Engineering Contradiction:
Improvethermal energy storageVSAvoidsystem complexity
Core Design Contradiction:
Use of energy by stationary objectVSDevice complexity

Solution Approach 1:

The patent combines the PCM and metal hydride into a single composite material system, eliminating the need for separate vessels and piping. The PCM is dispersed within the metal hydride matrix, creating an integrated structure that performs both hydrogen storage and thermal energy storage functions in one component, thereby reducing system complexity while maintaining thermal energy storage capability

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The composite material serves multiple functions simultaneously: it acts as both a hydrogen storage medium (metal hydride) and a thermal energy storage medium (PCM). This multi-functionality eliminates the need for separate dedicated systems for each function, reducing overall system complexity and component count

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Temperature

If PCMs are used for thermal management, then heat transfer is improved, but system cost increases

Engineering Contradiction:
Improveheat transfer efficiencyVSAvoidsystem cost
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The patent creates a composite material by dispersing PCM particles within the metal hydride matrix. This composite structure enables effective heat transfer management through the PCM's phase change properties while avoiding the high costs associated with separate PCM vessels, piping, and associated infrastructure. The composite approach integrates thermal management functionality directly into the storage material

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent selects PCMs with specific melting temperatures matched to the metal hydride's desorption and absorption temperature ranges. By optimizing the PCM's thermal parameters (melting point, latent heat) to match the operational temperature profile of the metal hydride, effective thermal management is achieved at lower system costs compared to using PCMs with mismatched parameters that would require additional thermal management infrastructure

Inventive Principle:
Principle #35Parameter changes

3Temperature

If PCMs are dispersed within metal hydride, then heat transfer efficiency is enhanced, but material homogeneity becomes difficult to achieve

Engineering Contradiction:
Improveheat transfer efficiencyVSAvoidmaterial homogeneity
Core Design Contradiction:
TemperatureVSStability of the object's composition

Solution Approach 1:

The patent employs local dispersion of PCM particles within the metal hydride matrix, creating regions with optimized local thermal properties. The PCM is distributed at appropriate concentrations and spatial arrangements within the matrix, ensuring sufficient heat transfer efficiency at local levels while maintaining overall material stability and compositional consistency throughout the bulk material

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enhances heat transfer efficiency between the hydride and PCM, simplifies the system design, reduces costs, and improves the overall performance of hydrogen storage by effectively managing thermal energy without additional structural complexity.

Implementation Method 1

a composite material comprising a powder or pellets of a hydride and a phase changing material (PCM), wherein the PCM is an encapsulated phase changing material (EPCM) which is homogeneously dispersed within the powder or pellets of the hydride

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

the phase changing material (PCM) is selected so as to have a melting area ΔTf between the hydrogen desorption temperature (T1) at the operating desorption pressure and the hydrogen absorption temperature (T2) at the operating absorption pressure

Methodology Applied
Scientific EffectLatent heat: Latent Heat

Implementation Method 3

the hydrogenation, i.e. the absorption of hydrogen in the hydride storage, is an exothermic reaction, where heat is created

Methodology Applied
Scientific EffectHydrogen absorption: Absorption (physical)

Implementation Method 4

the dehydrogenation, i.e. the release of hydrogen from the hydride, is an endothermic reaction, where heat is needed

Methodology Applied
Scientific EffectHydrogen desorption: Desorption

Implementation Method 5

This solution enhances heat transfer efficiency between the hydride and PCM

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Data Source

PatentUS11845659B2Integrated material and process for integrated operation of a hydride storage system
Publication Date: 2023.12.19 HELMHOLTZ ZENTRUM HEREON GMBH

AI summary

The present invention relates to a composite material for hydrogen storage based on metal hydrides and to a method of operating a hydrogen storage system based on metal hydrides capable of releasing and absorbing hydrogen. Such hydrogen storage systems based on metal hydrides may be applicable as a fuel source for a fuel cell. The composite material for hydrogen storage comprises a powder or pellets of a hydride and a phase changing material (PCM), wherein the PCM is an encapsulated phase changing material (EPCM) which is homogeneously dispersed within the powder or pellets of the hydride.