Hydrogen Bonding Coating for CMP Membrane Adhesion

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Solution Overview

Problem

In the chemical mechanical polishing (CMP) process, existing membranes often experience weak Van der Waals-based bonding forces with wafers, leading to separation and breakage during polishing, which hampers semiconductor productivity and increases production costs.

Innovation Solution

A membrane coating compound with functional groups capable of hydrogen bonding, such as catechol structures and polymers like polydopamine, is applied to improve adhesion between the membrane and the wafer, enhancing the bonding force and preventing separation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If existing membranes are used with Van der Waals-based bonding, then the membrane structure is simple and easy to manufacture, but the bonding force with the wafer is weak leading to separation and breakage

Engineering Contradiction:
Improvebonding forceVSAvoidmembrane structure complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining the membrane with a coating layer containing compounds that have functional groups capable of hydrogen bonding. This composite structure integrates the simplicity of the original membrane with the enhanced bonding capabilities of the coating layer, resolving the contradiction between structural simplicity and bonding strength.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical parameters of the membrane surface by introducing functional groups (such as hydroxyl, carboxyl, or amine groups) that can form hydrogen bonds. This parameter change transforms the bonding mechanism from weak Van der Waals forces to stronger hydrogen bonding, increasing the bonding force while maintaining the overall membrane structure.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a coating layer with hydrogen bonding capability is added, then the adhesion force increases preventing separation, but the device complexity and manufacturing difficulty increase

Engineering Contradiction:
Improveadhesion stabilityVSAvoidcoating application complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The coating layer acts as an intermediary between the membrane and the wafer, providing hydrogen bonding capability without requiring changes to the fundamental membrane structure or the wafer. This intermediary layer enables strong adhesion while keeping the manufacturing process relatively simple by focusing modifications on the coating material rather than the entire system.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If hydrogen bonding compounds are used in the coating layer, then wafer separation and breakage are reduced, but the production cost increases

Engineering Contradiction:
Improvesemiconductor productivityVSAvoidproduction cost
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent optimizes the concentration and type of functional groups in the coating layer to achieve the minimum necessary hydrogen bonding capability for preventing wafer separation. By carefully controlling these parameters, the patent reduces the amount of expensive coating material needed while maintaining sufficient adhesion strength, thereby reducing production costs while improving productivity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of hydrogen bonding significantly increases the adhesion force, reducing wafer separation and breakage, thereby improving semiconductor productivity and reducing production costs by ensuring stable and efficient CMP processes.

Implementation Method 1

the coating layer includes a compound including a functional group capable of hydrogen bonding, and the wafer is fixable by hydrogen bonding between the compound of the coating layer and the wafer

Methodology Applied
Scientific EffectHydrogen bonding: Chemical Bonding

Implementation Method 2

existing membranes often experience weak Van der Waals-based bonding forces with wafers

Methodology Applied
Scientific EffectVan der Waals force: Van der Waals Force

Data Source

PatentUS20240189960A1Membrane coating compound for chemical mechanical polishing process, membrane including the same, and polishing apparatus including the same
Publication Date: 2024.06.13 SAMSUNG ELECTRONICS CO LTD
  • US20240189960A1 patent drawing
  • US20240189960A1 patent drawing
  • US20240189960A1 patent drawing

AI summary

A membrane coating compound for a chemical mechanical polishing process, a membrane structure for a chemical mechanical polishing process, and a polishing apparatus for a chemical mechanical polishing process in which a wafer is holdable under pressure on the polishing apparatus, the membrane coating compound includes a functional group capable of hydrogen bonding.