Hydrogen Buffer Container Impurity Monitoring and Control

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Solution Overview

Problem

Current hydrogen filling station methods fail to ensure the required purity of hydrogen for fuel cells without significant additional cost, often resulting in costly purification steps or energy wastage due to impurities in the hydrogen supply.

Innovation Solution

A method that determines the current concentration of impurities in the hydrogen buffer container during filling and compares it to a threshold, stopping the filling process when the concentration reaches the threshold, allowing for real-time monitoring and switching to another buffer container to maintain purity and reduce waste.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If expensive purification steps (cryogenic adsorbent bed or palladium membranes) are added upstream of filling stations, then hydrogen purity meets fuel cell specifications, but cost increases significantly

Engineering Contradiction:
Improvehydrogen purityVSAvoidcost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces expensive mechanical/chemical purification systems (cryogenic adsorbent beds, palladium membranes) with a sensor-based monitoring and control system that detects impurity concentrations and automatically manages buffer containers to maintain purity without physical purification steps

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The system uses real-time impurity concentration measurements to automatically control the filling process and buffer container selection, allowing the filling station to self-regulate hydrogen purity without external purification infrastructure

Inventive Principle:
Principle #25Self-service

2Reliability

If liquid hydrogen or cryogenic purification is used to ensure purity, then hydrogen quality meets specifications, but cost increases by 40% to 100%

Engineering Contradiction:
Improvehydrogen purityVSAvoidcost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention substitutes complex cryogenic purification infrastructure and liquid hydrogen storage systems with an electronic monitoring and control system that uses sensors and automated buffer management to achieve the same purity guarantee at minimal cost

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The system changes the control parameter from physical state manipulation (cryogenic temperatures, phase changes) to real-time concentration monitoring and process control, maintaining purity through information-based control rather than energy-intensive physical treatment

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If gas analyzer is installed upstream of compressors to validate purity, then impurity detection is achieved, but compressor shutdown and energy wastage occur when impurity threshold is exceeded

Engineering Contradiction:
Improveimpurity detectionVSAvoidenergy wastage
Core Design Contradiction:
Measurement precisionVSLoss of energy

Solution Approach 1:

The system performs preliminary impurity detection and takes preventive action by selecting appropriate buffer containers before contamination occurs, avoiding the need to shut down the compressor or vent hydrogen to atmosphere

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The system uses real-time impurity concentration feedback from sensors to dynamically control buffer container selection and filling operations, continuously adapting to maintain purity without interrupting compressor operation or wasting energy

Inventive Principle:
Principle #23Feedback

4Reliability

If compressor is shut down manually when impurity threshold is exceeded, then hydrogen purity is maintained, but operational time is lost and station operates in degraded mode

Engineering Contradiction:
Improvehydrogen purityVSAvoidfilling capacity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The system pre-fills multiple buffer containers with pure hydrogen before impurity accumulation occurs, so when purification is needed, the compressor can continue operating using pre-stored pure hydrogen from buffers, maintaining both purity and productivity

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The system ensures continuous compressor operation by using buffer containers as intermediaries that decouple the compressor from the purification process, allowing the compressor to run continuously while buffer containers are selectively used or refilled, eliminating downtime and maintaining full productivity

Inventive Principle:
Principle #20Continuity of useful action

Data Source

PatentEP3019786B1Gas filling method and station
Publication Date: 2019.11.20 LAIR LIQUIDE SA POUR LETUDE & LEXPLOITATION DES PROCEDES GEORGES CLAUDE
  • EP3019786B1 patent drawingFigure 1~3
  • EP3019786B1 patent drawing
  • EP3019786B1 patent drawing

AI summary

A method for filling at least one buffer container (1, 2, 3) of a hydrogen filling station (100), the station (100) comprising a fluid circuit (11, 12, 13, 4, 5, 6) linked to said at least one buffer container (1, 2, 3), the circuit of the filling station (100) comprising a first end linked to at least one source of hydrogen gas (14, 15), the circuit (11, 12, 13, 4, 5, 6) comprising a second end provided with a transfer conduit (6) intended to be removably connected to a tank (8), the method being characterised in that it comprises a step (9, 10) of determining the current concentration of at least one impurity in the hydrogen in the buffer container (1, 2, 3) during the filling of same, a step of comparing said current concentration of the impurity relative to a predefined threshold concentration and, when the current concentration of the at least one impurity reaches said threshold concentration, stopping the filling of said buffer container (1, 2, 3).