Electrochemical Hydrogen Sensor for Real-Time Contaminant Detection

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Solution Overview

Problem

Current methods for monitoring hydrogen purity in fuel cell deployments are limited to laboratory settings, making it difficult to detect contaminants in real-time, which can lead to significant quantities of contaminated hydrogen being dispensed before issues are identified.

Innovation Solution

A hydrogen monitoring system comprising multiple electrochemical cells with working and counter electrodes, an electrolyte, and an electrical circuit that can be integrated into a hydrogen delivery system to detect contaminants in real-time, using a software program to analyze data and provide decision labels based on contaminant thresholds.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If laboratory analysis methods are used for hydrogen purity testing, then measurement precision is improved, but loss of time increases and productivity decreases

Engineering Contradiction:
Improvehydrogen purity measurement precisionVSAvoidtime for contaminant detection
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent replaces complex mechanical laboratory analysis equipment with an electrochemical sensing system that uses electrical fields and chemical reactions to detect contaminants. The sensor system substitutes physical laboratory procedures with automated electrochemical measurements, achieving both high precision and rapid results simultaneously

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the measurement parameters by using electrochemical potential and current measurements instead of traditional laboratory analytical methods. By monitoring electrical parameters in real-time as hydrogen flows through the sensor, the system achieves rapid contaminant detection without sacrificing measurement precision

Inventive Principle:
Principle #35Parameter changes

2Productivity

If real-time monitoring is implemented, then productivity is improved and loss of time is reduced, but device complexity increases

Engineering Contradiction:
Improvehydrogen dispensing speedVSAvoidmonitoring system complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The monitoring system is divided into separate functional modules: electrochemical sensing elements for contaminant detection, signal processing circuitry for data analysis, and control systems for decision-making. This segmentation allows real-time monitoring capability while managing complexity through modular design that can be integrated into existing hydrogen delivery infrastructure

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The sensor system is designed to detect multiple types of contaminants simultaneously using a single integrated platform. The electrochemical sensor array can identify various impurities in hydrogen fuel, providing universal monitoring capability that justifies the added complexity through enhanced productivity and safety

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Measurement precision

If laboratory testing procedures are followed, then measurement precision is improved, but ease of operation deteriorates

Engineering Contradiction:
Improvecontaminant level measurement precisionVSAvoidhydrogen purity testing operation
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The electrochemical sensor system performs automated contaminant detection without requiring skilled laboratory personnel. The system self-calibrates, automatically processes signals, and provides real-time feedback on hydrogen purity, making the operation simple and accessible while maintaining high measurement precision through built-in reference electrodes and standardized protocols

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables real-time detection of hydrogen contaminants, preventing the dispensing of contaminated hydrogen and ensuring the reliability and durability of fuel cell operations.

Implementation Method 1

a plurality of sensing elements that individually comprise a working electrode, a counter electrode, an insulating layer located in between the working electrode and the counter electrode, a catalyst located on an end of both the working electrode and the counter electrode, an electrolyte located on the end of the sensing elements on both the working electrode and the counter electrode, between the working electrode and the counter electrode, and in contact with the catalyst

Methodology Applied
Scientific EffectElectrochemical reactions: Redox Reactions

Data Source

PatentEP3635390B1Hydrogen monitoring and delivery components and methods
Publication Date: 2023.07.26 SKYRE INC
  • EP3635390B1 patent drawingFigure 1A~1B
  • EP3635390B1 patent drawingFigure 2~3B
  • EP3635390B1 patent drawingFigure 4~5

AI summary

In an embodiment, a hydrogen monitoring system comprises a plurality of sensing elements that individually comprise a working electrode, a counter electrode, an insulating layer located in between the working electrode and the counter electrode, a catalyst located on an end of both the working electrode and the counter electrode, an electrolyte located on the end of the sensing elements on both the working electrode and the counter electrode, between the working electrode and the counter electrode, and in contact with the catalyst, and an electrical circuit located on an opposite end of the sensing element that connects the working electrode and the counter electrode.