Stable Hydronium Electrolyte Composition for Aqueous pH Adjustment

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Solution Overview

Problem

Existing technologies struggle to produce stable and effective electrolytes that can be used in aqueous solutions to achieve desired pH levels, particularly in applications requiring low pH values or adjustments in alkaline solutions.

Innovation Solution

A novel electrolyte composition with the chemical structure [Hx⁢O(x-1)2+(H2⁢O)y]⁢Z is introduced, where x is an odd integer ≥3, y is an integer between 1 and 20, and Z is a polyatomic or monoatomic ion. This composition forms stable hydronium ion complexes that can be added to aqueous solutions to adjust pH levels effectively.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electrolytes are used to adjust pH levels, then the solution can achieve the desired pH, but the electrolyte stability and effectiveness deteriorate, especially in low pH or alkaline solutions

Engineering Contradiction:
Improveelectrolyte stabilityVSAvoidpH adjustment effectiveness
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent changes the chemical parameters of the electrolyte by using oxonium ion derivatives with specific molecular structures (formula 1) instead of conventional electrolytes. This structural parameter change enables the electrolyte to maintain stability while effectively adjusting pH levels in both acidic and alkaline solutions, resolving the contradiction between stability and effectiveness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs composite molecular structures comprising oxonium ions combined with specific counterions (Z-) in defined stoichiometric ratios. This composite approach creates an electrolyte that exhibits enhanced stability and pH adjustment capability simultaneously, overcoming the limitations of simple conventional electrolytes.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If strong acids are used to achieve low pH values, then the desired pH level is reached, but the solution exhibits perceivable reactive properties that may cause unwanted side effects

Engineering Contradiction:
ImprovepH level controlVSAvoidreactive properties
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The oxonium ion derivative acts as an intermediary substance that provides pH control without exhibiting the harsh reactive properties of strong acids. The unique molecular structure of the oxonium ion allows it to function as a mild acidifying agent, achieving precise pH control while minimizing harmful reactions with other solution components.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

By changing the chemical nature of the acidifying agent from conventional strong acids to oxonium ion derivatives with specific structural parameters (formula 1), the invention achieves the same pH control function while fundamentally altering the reactivity profile, thereby eliminating harmful side effects.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If conventional electrolytes are added to aqueous solutions, then the pH can be adjusted, but the free acid to total acid ratio changes, affecting the solution composition

Engineering Contradiction:
ImprovepH adjustment capabilityVSAvoidfree acid to total acid ratio
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The oxonium ion derivative is designed to self-regulate its dissociation behavior in solution, maintaining a consistent free acid to total acid ratio through its inherent molecular structure. This self-service property ensures that pH adjustment does not inadvertently alter the overall composition stability, as the electrolyte automatically balances its ionization state.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The stable hydronium ion complexes alter the acid functionality of the resulting solvent without changing the free acid to total acid ratio, allowing for effective pH adjustments in solutions with initial pH between 6 and 8, and even in alkaline solutions without perceivable reactive properties.

Implementation Method 1

water molecules are effective in stabilizing unbalanced charges present in solution. It is believed that water molecules present in an aqueous solution stabilize any unbalanced charges and yield a charge balanced solution.

Methodology Applied
Scientific EffectElectrostatic charge balancing: Coulomb's Law

Implementation Method 2

A novel electrolyte composition with the chemical structure [Hx⁢O(x-1)2+(H2⁢O)y]⁢Z is introduced, where x is an odd integer ≥3, y is an integer between 1 and 20, and Z is a polyatomic or monoatomic ion. This composition forms stable hydronium ion complexes that can be added to aqueous solutions to adjust pH levels effectively.

Methodology Applied
Scientific EffectIon complex formation: Solvation

Data Source

PatentUS12300444B2Stable electrolyte material and solvent material containing same
Publication Date: 2025.05.13 TYGRUS LLC
  • US12300444B2 patent drawing
  • US12300444B2 patent drawing
  • US12300444B2 patent drawing

AI summary

A composition of matter having the following chemical structure:[Hx⁢O(x-1)2]⁢Zywherein x is an odd integer ≥3;y is an integer between 1 and 20; andZ is one of a monoatomic ion from Groups 14 through 17 having a charge value between −1 and −3 or apolyatomic ion having a charge between −1 and −3.