Hydrophobic Coated Anode Lead Wire for Delamination-Resistant Capacitors

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Solution Overview

Problem

Solid electrolytic capacitors face delamination issues due to residual moisture vaporization during high-temperature manufacturing, leading to rapid deterioration of electrical properties.

Innovation Solution

A solid electrolytic capacitor design featuring a sintered porous anode body, a dielectric layer, and a solid electrolyte, with an anode lead wire having a hydrophobic coating and recessed regions to enhance adhesion and prevent delamination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If high temperature reflow is used during capacitor manufacture, then manufacturing process is completed, but residual moisture vaporizes causing micro-cracks and delamination

Engineering Contradiction:
Improvemanufacturing process completionVSAvoidcasing material adhesion
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The anode lead wire surface is pre-treated with a hydrophobic coating and recessed region formation before the reflow process. This preliminary preparation allows the lead wire to repel moisture vapor during subsequent high-temperature processing, preventing the vapor from penetrating into the casing material and causing delamination.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The hydrophobic coating on the anode lead wire converts the harmful effect of moisture vapor into a beneficial outcome by actively repelling the vapor during high-temperature reflow. The coating transforms what would be a damaging condition (moisture exposure at high temperature) into a protective mechanism that prevents delamination while allowing the manufacturing process to proceed.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Ease of manufacture

If conventional anode lead wire design is used, then manufacturing is simple, but delamination occurs at high temperatures

Engineering Contradiction:
Improvelead wire fabricationVSAvoidthermal stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The surface properties of the anode lead wire are modified by applying a hydrophobic coating and creating recessed regions. These parameter changes in surface chemistry and topology enable the lead wire to resist moisture vapor adhesion during thermal processing, significantly improving thermal stability without complicating the overall manufacturing process.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The recessed regions created on the anode lead wire surface provide a textured, porous-like structure that enhances the effectiveness of the hydrophobic coating. This surface geometry prevents moisture vapor from making direct contact with the bulk lead wire material, reducing capillary action and adhesion forces that would otherwise cause delamination at high temperatures.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The capacitor exhibits improved electrical performance with reduced equivalent series resistance and capacitance stability at high temperatures and humidity levels, maintaining performance over extended periods.

Implementation Method 1

A hydrophobic coating is disposed on at least a portion of the external surface of the anode lead wire

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Data Source

PatentUS11222755B2Delamination-resistant solid electrolytic capacitor
Publication Date: 2022.01.11 KYOCERA AVX COMPONENTS CORP
  • US11222755B2 patent drawing
  • US11222755B2 patent drawing
  • US11222755B2 patent drawing

AI summary

A solid electrolytic capacitor that comprises a capacitor element that contains a sintered porous anode body, a dielectric that overlies the anode body, and a solid electrolyte that overlies the dielectric is provided. An anode lead wire extends from the capacitor element in a longitudinal direction, wherein the lead wire defines an external surface having a plurality of distinct recessed regions that are spaced apart along the longitudinal direction. A hydrophobic coating is disposed on at least a portion of the external surface of the anode lead wire. Further, an anode termination is in electrical connection with the anode lead wire and a cathode termination is in electrical connection with the solid electrolyte.