Down-flow Hydroprocessing Reactor Nozzle Mixing

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Solution Overview

Problem

In down-flow hydroprocessing reactors, poor interbed fluid mixing leads to temperature maldistribution, hot spots, and reduced catalyst lifetime, necessitating improved nozzle devices for efficient gas and liquid distribution to maintain reactor performance and prevent runaway reactions.

Innovation Solution

A nozzle device with a converging-diverging nozzle restrictor and offset gas and liquid inlets, designed to enhance mixing and reduce pressure drop, featuring a nozzle body with distinct zones for gas and liquid introduction and a frustoconical nozzle restrictor for efficient fluid mixing and distribution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional nozzles are used for gas and liquid distribution, then the reactor can operate, but temperature maldistribution and hot spots occur due to poor interbed fluid mixing

Engineering Contradiction:
Improvetemperature uniformityVSAvoidcatalyst lifetime
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The nozzle is divided into distinct functional zones: a gas inlet zone with multiple gas inlet ports, a liquid inlet zone with liquid inlet ports, and an exit zone. This segmentation allows independent optimization of gas and liquid flow paths, enabling effective mixing of the two phases while maintaining temperature uniformity and preventing hot spots that would otherwise degrade catalyst lifetime.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different portions of the nozzle are designed with different properties: the gas inlet zone has multiple offset ports for gas distribution, the liquid inlet zone has dedicated liquid ports, and the exit zone provides controlled discharge. This local differentiation of functionality ensures that gas and liquid are introduced and mixed in specific regions, achieving uniform temperature distribution throughout the reactor bed.

Inventive Principle:
Principle #3Local quality

2Temperature

If mixing intensity is increased to improve temperature uniformity, then temperature maldistribution is reduced, but pressure drop through the nozzle increases

Engineering Contradiction:
Improvetemperature uniformityVSAvoidpressure drop
Core Design Contradiction:
TemperatureVSStress or pressure

Solution Approach 1:

The gas and liquid inlet zones are positioned to merge their flows within the nozzle body before exit. The offset ports are arranged so that gas and liquid streams combine and mix in a controlled manner within the nozzle, achieving effective mixing without requiring excessive pressure drop. The merged flow then exits uniformly to distribute both phases throughout the reactor bed.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The nozzle utilizes three-dimensional spatial arrangement of offset gas and liquid inlet ports to achieve mixing. Rather than relying solely on increased flow velocity (one dimension), the invention employs spatial distribution of multiple inlet ports at different locations and angles, creating multi-dimensional flow patterns that enhance mixing efficiency while maintaining acceptable pressure drop levels.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nozzle device achieves effective mixing and distribution of gas and liquid phases, reducing pressure drop and operational costs, while improving reactor performance and catalyst longevity by maintaining uniform temperature and flow, thus preventing hot spots and runaway reactions.

Implementation Method 1

The nozzle provides effective mixing of an existing mixing volume in mixing the gas and liquid phases of two-phase systems, while providing for a reduced pressure drop through the nozzle

Methodology Applied
Scientific EffectFluid mixing: Turbulence

Data Source

PatentEP3787785B1Nozzle for a down-flow hydroprocessing reactor
Publication Date: 2023.08.23 CHEVRON USA INC

AI summary

An improved nozzle device for a down-flow hydroprocessing reactor is disclosed. The down-flow nozzle is useful in the petroleum and chemical processing industries in catalytic reactions of hydrocarbon feedstocks in the presence of hydrogen, at an elevated temperature and pressure, to provide for the mixing and distribution of gas and liquid to reactor catalyst beds. Typical hydroprocessing applications include hydrotreating, hydrofinishing, hydrocracking and hydrodewaxing.