Catalyst Replacement in Operating Hydroprocessing Reactor Trains

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Solution Overview

Problem

Hydroprocessing systems face frequent catalyst deactivation, leading to increased production losses and operational costs due to the need for frequent shutdowns to replace spent catalysts, which disrupts manufacturing and reduces flexibility in processing various crude oils.

Innovation Solution

A method and system for replacing a spent catalyst in an operating hydroprocessing system by activating a valving system to disrupt operation of select reactor trains, using a gas processing system to decontaminate the catalyst, removing the decontaminated catalyst, and loading fresh catalysts while maintaining at least 25% of the system's capacity, allowing for continuous operation and reduced downtime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the entire system is shut down to replace spent catalyst, then the catalyst can be properly sanitized and replaced, but production is lost and operating costs increase

Engineering Contradiction:
Improvecatalyst replacement effectivenessVSAvoidhydrocarbon production
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The system is divided into multiple independent reactor trains (first, second, third reactor trains) that can be operated separately. The valving system allows isolation of individual reactor trains for catalyst replacement while maintaining operation of other trains, enabling segment-by-segment maintenance without complete system shutdown.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The hydroprocessing system maintains continuous operation through multiple reactor trains. While one reactor train undergoes catalyst replacement, other reactor trains continue processing feed fluid, ensuring uninterrupted hydrocarbon production and eliminating complete system shutdowns.

Inventive Principle:
Principle #20Continuity of useful action

2Manufacturing precision

If catalyst replacement is performed frequently to meet product requirements, then product quality improves, but system shutdowns increase and flexibility decreases

Engineering Contradiction:
Improveproduct qualityVSAvoidmanufacturing flexibility
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The multiple reactor trains can be independently managed, allowing frequent catalyst replacement in one train without affecting operation of other trains. This segmentation enables maintaining high product quality standards while preserving overall system flexibility.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system dynamically adjusts operation by switching between different reactor train configurations. The valving system enables flexible reconfiguration to accommodate catalyst replacement schedules while maintaining continuous production and adapting to different processing requirements.

Inventive Principle:
Principle #15Dynamics

3Reliability

If the system is shut down for weeks to replace catalyst, then complete catalyst replacement is achieved, but production loss and profit loss increase significantly

Engineering Contradiction:
Improvecatalyst replacement completenessVSAvoidsystem downtime
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The catalyst replacement process is segmented across multiple reactor trains, allowing replacement to occur in phases rather than requiring complete system shutdown. This reduces total downtime while ensuring thorough catalyst replacement across all trains over time.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Hydrocarbon production continues without interruption through operating reactor trains while catalyst replacement occurs in isolated trains. This maintains continuous useful action and eliminates weeks-long shutdowns, significantly reducing production loss and profit loss.

Inventive Principle:
Principle #20Continuity of useful action

4Productivity

If multiple reactor trains are operated simultaneously, then production capacity is maintained, but system complexity increases

Engineering Contradiction:
Improveproduction capacityVSAvoidsystem complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The system uses identical, modular reactor train designs that can be independently operated. This standardization reduces operational complexity despite having multiple trains, as each train follows the same operational protocol and can be managed independently through the valving system.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The valving system provides universal control functionality across all reactor trains, enabling a single control mechanism to manage multiple trains. This multi-functionality reduces overall system complexity by using standardized components and control procedures across all reactor units.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables continuous hydrocarbon production with reduced downtime and increased manufacturing flexibility by maintaining a significant portion of the system's capacity during catalyst replacement, minimizing production losses and operational costs.

Implementation Method 1

activating a gas processing system to remove a contaminant from a spent catalyst to form a decontaminated catalyst

Methodology Applied
Scientific EffectGas processing:

Data Source

PatentUS20230398533A1Methods for replacing a spent catalyst of a reactor train of an operating hydroprocessing system
Publication Date: 2023.12.14 SHELL USA INC
  • US20230398533A1 patent drawing
  • US20230398533A1 patent drawing
  • US20230398533A1 patent drawing

AI summary

The present disclosure relates to a method for replacing a catalyst of a reactor train of an operating hydroprocessing system comprising a plurality of reactor trains comprising a catalyst and each configured to receive a feed fluid and combine a portion of the feed fluid with a hydrogen stream over the catalyst to generate a hydrotreated fluid, the method comprising activating a valving system of the operating hydroprocessing system to disrupt operation of a select reactor train comprising a spent catalyst to form a disrupted reactor train while maintaining operation of at least one other reactor train; activating the gas processing system to form a decontaminated catalyst, removing the decontaminated catalyst from the disrupted reactor train to form a catalyst free reactor train; loading the catalyst free reactor train with a fresh catalyst to produce a charged reactor train; and restoring operation of the catalyst charged reactor train.