III-V Channel 3D NAND Interface Quality

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Solution Overview

Problem

Incorporating III-V channels into 3D memory with vertical NAND strings poses challenges such as providing a good interface between the III-V channel and tunnel dielectric, achieving high electron mobility, and forming cost-effective fabrication techniques that result in high-quality NAND channels with low defects and leakage.

Innovation Solution

The use of a III-V compound channel with a mono-crystalline structure, specifically InGaAs, and a tunnel dielectric of aluminum oxide (Al2O3) to enhance interface quality and mobility, along with growth techniques like self-directed epitaxial growth to form III-V NAND channels in memory holes, and forming a metal-III-V alloy at the drain end for good Ohmic contact.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional silicon channels are used in 3D vertical NAND strings, then fabrication is simpler and cost-effective, but electron mobility is limited and performance is constrained

Engineering Contradiction:
Improveelectron mobilityVSAvoidfabrication complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the material parameter from silicon to III-V compound semiconductors (InGaAs, InAlAs, GaAs, GaSb, InP) to achieve higher electron mobility and hole mobility, directly addressing the performance limitation of conventional silicon channels while maintaining the vertical NAND string structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures including metal-III-V semiconductor alloys at the drain end for Ohmic contact, and interfaces III-V channels with tunnel dielectrics (Al2O3, HfO2, SiO2) and charge trapping layers (SiN, AlN) to resolve interface quality issues while achieving high electron mobility

Inventive Principle:
Principle #40Composite materials

2Productivity

If III-V compound channels are used to achieve high electron mobility, then read-write efficiency improves, but interface quality between channel and tunnel dielectric becomes challenging

Engineering Contradiction:
Improveread-write efficiencyVSAvoidinterface quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent introduces aluminum oxide (Al2O3) as an intermediary tunnel dielectric layer that forms a high-quality interface with III-V compound channels, and uses charge trapping layers (SiN, AlN) as intermediate structures between the channel and blocking dielectric, resolving the interface quality challenge

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces conventional silicon-based interfaces with III-V compound semiconductor interfaces combined with high-k dielectric tunnel barriers, substituting the traditional silicon-tunnel dielectric interface system with a new material system that achieves both high electron mobility and good interface quality

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Quantity of substance

If higher density storage is implemented using 3D stacked structure, then storage capacity increases, but chip size and program disturb increase

Engineering Contradiction:
Improvestorage capacityVSAvoidprogram disturb
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent applies local quality by implementing selective area epitaxial growth to form III-V compound channels only in specific memory hole regions, and uses localized charge trapping layers and tunnel dielectric structures to confine electric fields, reducing program disturb to adjacent cells while maintaining high storage capacity

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent transitions from planar 2D memory architecture to 3D vertical stacked architecture with vertical NAND strings extending through multiple tiers, increasing storage capacity by utilizing the third dimension while maintaining compact chip footprint and reducing program disturb through vertical isolation

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

4Ease of manufacture

If conventional fabrication techniques are used, then manufacturing is cost-effective, but defect density in NAND channels increases

Engineering Contradiction:
Improvemanufacturing costVSAvoiddefect density
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent employs self-directed epitaxial growth where the memory hole structure itself guides the growth of III-V compound semiconductor nanowires, and uses catalyst-free vapor-liquid-solid growth mechanisms, enabling cost-effective fabrication while achieving low defect density through self-organization and minimal external intervention

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in high electron mobility, low sub-threshold slope, and reduced select transistor leakage, leading to improved read-write efficiency and simplified chip design with reduced program disturb and chip size.

Implementation Method 1

The III-V compound provides for high electron mobility transistor cells (as well as high hole mobility)

Methodology Applied
Scientific EffectElectron mobility: Conduction (electrical)

Implementation Method 2

a tunnel dielectric of aluminum oxide (Al2O3) to enhance interface quality and mobility

Methodology Applied
Scientific EffectTunneling: Conduction (electrical)

Implementation Method 3

growth techniques like self-directed epitaxial growth to form III-V NAND channels in memory holes

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Implementation Method 4

forming a metal-III-V alloy at the drain end for good Ohmic contact

Methodology Applied
Scientific EffectOhmic contact: Conduction (electrical)

Data Source

PatentUS9685454B2Method of forming 3D vertical NAND with III-V channel
Publication Date: 2017.06.20 SANDISK TECHNOLOGIES LLC
  • US9685454B2 patent drawing
  • US9685454B2 patent drawing
  • US9685454B2 patent drawing

AI summary

Disclosed herein is 3D memory with vertical NAND strings having a III-V compound channel, as well as methods of fabrication. The III-V compound has at least one group III element and at least one group V element. The III-V compound provides for high electron mobility transistor cells. Note that III-V materials may have a much higher electron mobility compared to silicon. Thus, much higher cell current and overall cell performance can be achieved. Also, the memory device may have better read-write efficiency due to much higher carrier mobility and velocity. The tunnel dielectric of the memory cells may have an Al2O3 film in direct contact with the III-V NAND channel. The drain end of the NAND channel may be a metal-III-V alloy in direct contact with a metal region. The body of the source side select transistor could be formed from the III-V compound or from crystalline silicon.