Ink Composition for Organic Semiconductor Uniformity

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Solution Overview

Problem

Existing ink compositions for organic electroluminescence (EL) elements face issues with non-uniformity during storage and film formation due to the separation of components, leading to unstable ink ejection and variations in film thickness, which affect the properties of the light-emitting functional layer.

Innovation Solution

An ink composition comprising a hydrophilic solvent, a hydrophobic solvent, an amphiphic solvent, and a solute or dispersing element that changes phases upon evaporation, improving compatibility and solubility, thereby maintaining uniformity and controlling the drying process to achieve stable film thickness and reduced residual solvent levels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If inks having different physical properties are mixed to improve layer thickness uniformity, then the uniformity of film thickness is improved, but the ink components separate during storage leading to non-uniform composition

Engineering Contradiction:
Improveuniformity of film thicknessVSAvoiduniformity of ink composition during storage
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent changes the physical parameters of the solvent system by selecting specific combinations of hydrophilic solvents (e.g., alcohols, glycols) and hydrophobic solvents (e.g., aromatic hydrocarbons, halogenated hydrocarbons) with controlled solubility parameters. This parameter optimization ensures the ink maintains homogeneity during storage while providing controlled drying characteristics for uniform film formation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite solvent system comprising multiple components with different hydrophilicity. The specific combination of hydrophilic and hydrophobic solvents creates a synergistic effect where the hydrophilic solvent ensures good solubility of the organic semiconductor material while the hydrophobic solvent controls evaporation rate, achieving both storage stability and uniform film thickness.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If the ink is allowed to dry slowly to improve film thickness uniformity, then the uniformity of film thickness is improved, but residual solvent remains in the film inhibiting light-emitting properties

Engineering Contradiction:
Improveuniformity of film thicknessVSAvoidresidual solvent in film
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent segments the evaporation process into distinct stages by using solvents with different volatility. The hydrophobic solvent evaporates first providing a controlled initial drying phase that ensures uniform film formation, followed by complete evaporation of the hydrophilic solvent phase, eliminating residual solvent while maintaining film thickness uniformity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent exploits phase transitions of the solvent components during drying. The hydrophobic solvent transitions from liquid to vapor first due to its higher volatility, establishing uniform film thickness. Subsequently, the hydrophilic solvent completes the evaporation process, ensuring no residual solvent remains in the final film while maintaining the achieved uniformity.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition ensures uniformity of ink components and film thickness, stabilizes ink droplet drying, and enhances the properties of the organic semiconductor element by reducing residual solvent and improving luminous efficiency and emission lifetime.

Implementation Method 1

by including the amphiphilic solvent (third component), the compatibility between the hydrophilic solvent (first component) and the hydrophobic solvent (second component) is improved

Methodology Applied
Scientific EffectSolubilization: Solvation

Implementation Method 2

a fourth component which includes a solute or a dispersing element, and changes from one phase to two phases when the third component evaporates

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 3

both of the hydrophilic solvent (first component) and the hydrophobic solvent (second component) are used, the solubility of the solute with different hydrophilicity or the dispersibility of the dispersing element is ensured

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS10717886B2Ink composition, method for producing organic semiconductor element, organic semiconductor device, and method for producing optical element
Publication Date: 2020.07.21 SHIHENG CREATION LTD
  • US10717886B2 patent drawing
  • US10717886B2 patent drawing
  • US10717886B2 patent drawing

AI summary

An ink composition includes a first component which is a hydrophilic solvent, a second component which is a hydrophobic solvent, a third component which is an amphiphilic solvent, and a fourth component which includes a solute or a dispersing element, and when the third component evaporates, the ink composition is separated into a phase which mainly includes the first component and a phase which mainly includes the second component.