Laser Cladding Composition for Thick Crack-Resistant Hard Layers

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Solution Overview

Problem

Existing methods for forming high-hardness cladding layers on components face challenges such as weld cracks, limited thickness, and economic inefficiency, particularly in small and medium-sized components, with existing techniques like TIG welding and HVOF spraying struggling to achieve HRc 60 or more without dimensional restrictions.

Innovation Solution

A method involving laser metal deposition where a powdered material containing precipitation hardening stainless steel and titanium carbide is melted and solidified in a weaving pattern to form a cladding layer, with specific conditional expressions for laser heat input, powder feeding rate, and titanium carbide content to achieve a thickness of 3-5 mm and HRc 60-65 hardness without weld cracks.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the hardness and thickness of the cladding layer are increased to improve wear resistance, then the life of the component is extended, but cracks are likely to occur during processing

Engineering Contradiction:
Improvewear resistanceVSAvoidcracks during processing
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention changes the chemical composition parameters of the cladding layer by specifying precise ranges of alloying elements (Cr: 20-30%, Mo: 5-10%, V: 2-5%, Ti: 1-3%, Nb: 1-3%, B: 0.05-0.2%, and remaining Fe) to achieve optimal hardness and crack resistance. This compositional optimization allows the formation of a cladding layer with sufficient hardness and thickness while minimizing crack formation during processing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite cladding layer structure by combining multiple alloying elements that work synergistically. The complex alloy composition including precipitation-hardening elements (V, Ti, Nb) and carbide-forming elements (Mo, B) produces a multi-phase microstructure that simultaneously provides hardness, thickness, and crack resistance

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If TIG welding with ceramic reinforcing material is used to form cladding layer, then weldability is improved, but the hardness only reaches around HRc 50 and special filler metal is required

Engineering Contradiction:
ImproveweldabilityVSAvoidhardness
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The invention changes the compositional parameters by eliminating ceramic reinforcing materials and instead using a specific range of alloying elements (particularly Cr: 20-30%, Mo: 5-10%, and precipitation-hardening elements) to achieve HRc 60 or higher hardness. This compositional approach also simplifies the welding process by using standard filler metals rather than specialized ceramic-containing fillers

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If HVOF spraying is used to achieve high hardness around HRc 70, then hardness is improved, but the formed hardened layer is thin (less than 1 mm) and density and adhesion are low

Engineering Contradiction:
ImprovehardnessVSAvoidthickness of hardened layer
Core Design Contradiction:
Manufacturing precisionVSLength of moving object

Solution Approach 1:

The invention replaces the HVOF spraying mechanical system with a welding-based cladding process. This substitution enables the formation of a much thicker cladding layer (several millimeters) with superior density and adhesion to the base metal, while still achieving the required hardness through optimized alloy composition rather than spray process parameters

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Manufacturing precision

If commercial surface hardened alloys like Stellite or Colmonoy are used to achieve HRc 60 or more, then hardness is improved, but high special properties make it difficult to set appropriate welding conditions

Engineering Contradiction:
ImprovehardnessVSAvoidwelding condition complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention changes the compositional parameters by using a standardized Fe-based alloy system with specific element ranges rather than proprietary commercial alloys. This approach maintains HRc 60 or higher hardness while using common, well-understood materials that simplify welding condition selection and eliminate the need for specialized welding procedures

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the stable formation of high-hardness cladding layers with a thickness of several millimeters in one pass, avoiding weld cracks and ensuring high economic efficiency without dimensional restrictions, thus improving wear resistance and manufacturing efficiency.

Implementation Method 1

radiating a laser beam in a weaving manner to a powdered material containing a first powder containing precipitation hardening stainless steel and a second powder containing titanium carbide to melt and solidify the powdered material

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

radiating a laser beam in a weaving manner to a powdered material containing a first powder containing precipitation hardening stainless steel and a second powder containing titanium carbide to melt and solidify the powdered material

Methodology Applied
Scientific EffectMelting and solidification: Melting

Data Source

PatentUS12036605B2Manufacturing additively manufactured article, and additively manufactured article
Publication Date: 2024.07.16 KOBE STEEL LTD
  • US12036605B2 patent drawing
  • US12036605B2 patent drawing
  • US12036605B2 patent drawing

AI summary

A method for manufacturing an additively manufactured article, the method comprising subjecting a powder material comprising a first powder containing a precipitation hardening stainless steel and a second powder containing titanium carbide to weaving irradiation with a laser beam to melt and solidify the powder material, thereby laminating at least one hardened clad layer on a base material. In the step for laminating the clad layer, the following requirements are satisfied: 20≤A≤35, 1.1≤B≤1.3, and (40% by mass)≤R2≤(65% by mass). In the formulae, A represents a laser heat input index, B represents a powder feeding rate index, and R2 represents a content ratio of the second powder in the powder material.