Lead-Compound Dielectric Layers for High-Capacitance Low-Leakage Electrodes
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Solution Overview
Problem
Current dielectric materials face limitations in achieving a combination of high dielectric permittivity and large band gap, which restrict their application in nanoscale electronic devices, leading to reliability issues due to leakage currents.
Innovation Solution
The use of lead-containing compounds, oxyhalides, and phosphates with specific formulas, such as PbMgV2O7 and Pb13(Cl3O5)2, which offer a band gap greater than 1 eV and dielectric permittivity above 100, are integrated into electrode assemblies to form dielectric layers.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Productivity
If conventional dielectric materials are used, then device scaling is possible, but leakage currents increase and reliability deteriorates
Solution Approach 1:
The patent changes the material parameters by introducing lead-containing compounds with specific properties (band gap >1 eV, dielectric permittivity >100) to resolve the contradiction between device scaling and reliability. This parameter change enables nanoscale devices to maintain low leakage currents while achieving high capacitance.
Solution Approach 2:
The patent employs composite dielectric materials containing lead compounds combined with other oxides or compounds to achieve a synergistic effect. This composite approach allows the material to simultaneously provide high dielectric permittivity for capacitance and large band gap for leakage suppression, resolving the reliability issue during device scaling.
2Quantity of substance
If dielectric permittivity is increased to enhance capacitance, then band gap decreases leading to increased leakage
Solution Approach 1:
The patent fundamentally changes the material parameters by selecting lead-containing compounds that break the traditional inverse relationship between dielectric permittivity and band gap. These materials achieve both high permittivity (>100) and large band gap (>1 eV) simultaneously, enabling high capacitance without increasing leakage currents.
Solution Approach 2:
The patent converts the traditionally harmful effect of lead compounds (potential toxicity and instability) into a benefit by utilizing their unique electronic structure to achieve the desired electrical properties. The lead-containing compounds provide both high dielectric permittivity and large band gap, transforming a potentially problematic material class into a solution for suppressing leakage while maintaining high capacitance.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
These materials enhance capacitance and suppress leakage currents, providing improved reliability and performance in nanoscale electronic devices.
Implementation Method 1
the lead-containing compound, lead-containing oxyhalide, and lead-containing phosphate have a bandgap of greater than 1 eV
Implementation Method 2
dielectric permittivity above 100
Data Source
AI summary
An electrode assembly including a first electrode and a dielectric layer on the first electrode. The dielectric layer comprises a lead-containing compound of the formula PbMgV2O7, Pb2Te3O8, PbZnV2O7, Na2PbO2, PbP2O6, PbZnSiO4, Pb2In2Si2O9, Pb6(AsO4)[B(AsO4)4], PbAl2Si2O8, K4PbO3, Pb2TiAs2O9, Pb4O(VO4)2, Rb4PbO3, Pb2V2O7, Pb9Al8O21, Nd(Al3O6)(Pb2O2), Pb6Co9(TeO6)5, Pb3(B3O7)NO3, a lead-containing oxyhalide of the formula Pb13(Cl3O5)2, Pb13(Br3O5)2, Pb2OF2, Pb2CO3F2, Pb(AsO2)3Cl, Pb3O2(OH)Cl, Pb6(BO3)3OCl, Pb2B5O9I, Pb2B5O9Br, Pb2B5O9Cl, Pb5(AsO3)3Cl, Pb8Y6F32O, Pb(O2Pb3)2(BO3)Br3, Pb6LaO7Cl, a lead-containing phosphate of the formula Pb2PO4I, Pb2InP3O11, Pb2MoP3O11, Pb2Ni(PO4)2, Pb2VO(PO4), K2Pb(PO3)4, Pb3(MoO)3(PO4)5, Pb4O(PO4)2, RbPb(PO3)3, PbVO2PO4, Pb5(PO4)3F, Pb5(PO4)3Cl, Pb5(PO4)3I, PbP2O6, or a combination thereof. The electrode assembly can be particularly useful in various electronic devices.

