Lead-Compound Dielectric Layers for High-Capacitance Low-Leakage Electrodes

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Solution Overview

Problem

Current dielectric materials face limitations in achieving a combination of high dielectric permittivity and large band gap, which restrict their application in nanoscale electronic devices, leading to reliability issues due to leakage currents.

Innovation Solution

The use of lead-containing compounds, oxyhalides, and phosphates with specific formulas, such as PbMgV2O7 and Pb13(Cl3O5)2, which offer a band gap greater than 1 eV and dielectric permittivity above 100, are integrated into electrode assemblies to form dielectric layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional dielectric materials are used, then device scaling is possible, but leakage currents increase and reliability deteriorates

Engineering Contradiction:
Improvedevice scalingVSAvoiddevice reliability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the material parameters by introducing lead-containing compounds with specific properties (band gap >1 eV, dielectric permittivity >100) to resolve the contradiction between device scaling and reliability. This parameter change enables nanoscale devices to maintain low leakage currents while achieving high capacitance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite dielectric materials containing lead compounds combined with other oxides or compounds to achieve a synergistic effect. This composite approach allows the material to simultaneously provide high dielectric permittivity for capacitance and large band gap for leakage suppression, resolving the reliability issue during device scaling.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If dielectric permittivity is increased to enhance capacitance, then band gap decreases leading to increased leakage

Engineering Contradiction:
ImprovecapacitanceVSAvoidleakage currents
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent fundamentally changes the material parameters by selecting lead-containing compounds that break the traditional inverse relationship between dielectric permittivity and band gap. These materials achieve both high permittivity (>100) and large band gap (>1 eV) simultaneously, enabling high capacitance without increasing leakage currents.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the traditionally harmful effect of lead compounds (potential toxicity and instability) into a benefit by utilizing their unique electronic structure to achieve the desired electrical properties. The lead-containing compounds provide both high dielectric permittivity and large band gap, transforming a potentially problematic material class into a solution for suppressing leakage while maintaining high capacitance.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These materials enhance capacitance and suppress leakage currents, providing improved reliability and performance in nanoscale electronic devices.

Implementation Method 1

the lead-containing compound, lead-containing oxyhalide, and lead-containing phosphate have a bandgap of greater than 1 eV

Methodology Applied
Scientific EffectBand gap:

Implementation Method 2

dielectric permittivity above 100

Methodology Applied
Scientific EffectDielectric permittivity: Dielectric Permittivity

Data Source

PatentUS12558678B2Dielectric material comprising lead compound and method of making the same
Publication Date: 2026.02.24 SAMSUNG ELECTRONICS CO LTD
  • US12558678B2 patent drawing
  • US12558678B2 patent drawing

AI summary

An electrode assembly including a first electrode and a dielectric layer on the first electrode. The dielectric layer comprises a lead-containing compound of the formula PbMgV2O7, Pb2Te3O8, PbZnV2O7, Na2PbO2, PbP2O6, PbZnSiO4, Pb2In2Si2O9, Pb6(AsO4)[B(AsO4)4], PbAl2Si2O8, K4PbO3, Pb2TiAs2O9, Pb4O(VO4)2, Rb4PbO3, Pb2V2O7, Pb9Al8O21, Nd(Al3O6)(Pb2O2), Pb6Co9(TeO6)5, Pb3(B3O7)NO3, a lead-containing oxyhalide of the formula Pb13(Cl3O5)2, Pb13(Br3O5)2, Pb2OF2, Pb2CO3F2, Pb(AsO2)3Cl, Pb3O2(OH)Cl, Pb6(BO3)3OCl, Pb2B5O9I, Pb2B5O9Br, Pb2B5O9Cl, Pb5(AsO3)3Cl, Pb8Y6F32O, Pb(O2Pb3)2(BO3)Br3, Pb6LaO7Cl, a lead-containing phosphate of the formula Pb2PO4I, Pb2InP3O11, Pb2MoP3O11, Pb2Ni(PO4)2, Pb2VO(PO4), K2Pb(PO3)4, Pb3(MoO)3(PO4)5, Pb4O(PO4)2, RbPb(PO3)3, PbVO2PO4, Pb5(PO4)3F, Pb5(PO4)3Cl, Pb5(PO4)3I, PbP2O6, or a combination thereof. The electrode assembly can be particularly useful in various electronic devices.