Light-Emitting Element With Luminescence-Assisting Layers

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Solution Overview

Problem

Organic electroluminescent elements formed through liquid phase processes exhibit rapid luminance decrease and color changes due to variations in luminescent layer thickness, leading to reduced efficiency and shortened lifespan.

Innovation Solution

Incorporating a luminescent layer with first and second luminescence-assisting layers made of high-molecular-weight materials, similar to the host material, to prevent exciton deactivation and maintain optimal optical path length, thereby stabilizing the luminescent region and enhancing luminous efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If the thickness of the luminescent layer is increased, then the optical path length is increased, but the position and width of the luminescent region are changed causing color change

Engineering Contradiction:
Improveoptical path lengthVSAvoidluminescent region position and width
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The invention divides the luminescent layer into multiple sub-layers (first luminescent sub-layer, second luminescent sub-layer, third luminescent sub-layer) with different thicknesses and luminescent materials. This segmentation allows each sub-layer to contribute differently to the overall luminescence, maintaining stable color output while achieving sufficient optical path length for efficient luminescence.

Inventive Principle:
Principle #1Segmentation

2Stability of the object's composition

If the thickness of the luminescent layer is reduced, then the luminescent region position and width are stabilized, but excitons reach adjacent layers causing deactivation and reduced luminous efficiency

Engineering Contradiction:
Improveluminescent region position and widthVSAvoidluminous efficiency
Core Design Contradiction:
Stability of the object's compositionVSLoss of energy

Solution Approach 1:

The invention introduces blocking layers (hole blocking layer and electron blocking layer) as intermediaries between the luminescent layer and adjacent transport layers. These blocking layers prevent excitons from reaching and being deactivated in adjacent layers, thereby maintaining high luminous efficiency while allowing the luminescent layer to have reduced thickness for stable color output.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Stability of the object's composition

If the thickness of the luminescent layer is merely reduced, then the luminescent region is stabilized, but the optical path length becomes insufficient reducing luminance

Engineering Contradiction:
Improveluminescent region position and widthVSAvoidluminance
Core Design Contradiction:
Stability of the object's compositionVSIllumination intensity

Solution Approach 1:

The invention applies local quality by creating sub-layers with different characteristics - the first luminescent sub-layer has greater thickness for sufficient optical path length, while the second and third luminescent sub-layers have smaller thicknesses for stable luminescent region. Each sub-layer is positioned strategically to optimize both luminance and color stability.

Inventive Principle:
Principle #3Local quality

4Ease of manufacture

If liquid application is used to form the luminescent layer, then manufacturing is simplified and material usage is reduced, but rapid luminance decrease and color change occur

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidluminance stability and color consistency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention uses composite materials by combining multiple luminescent materials with different characteristics (fluorescent and phosphorescent materials) in different sub-layers. This composite approach maintains the ease of liquid application manufacturing while achieving stable luminance and color by distributing the luminescent function across multiple materials that compensate for each other's deficiencies.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents luminescent color change and enhances luminous efficiency while extending the lifespan of the light-emitting element by maintaining the luminescent region's stability and optimal optical path length.

Implementation Method 1

a luminescent layer which contains a luminescent material that emits light by applying a current between the anode and the cathode

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

a host material that helps the luminescent layer emit light

Methodology Applied
Scientific EffectEnergy transfer:

Implementation Method 3

The first luminescence-assisting layer has a function of preventing the excitons from being deactivated

Methodology Applied
Scientific EffectExciton diffusion blocking:

Data Source

PatentUS8952369B2Light-emitting element, light-emitting device, display device, and electronic apparatus
Publication Date: 2015.02.10 SHIHENG CREATION LTD
  • US8952369B2 patent drawing
  • US8952369B2 patent drawing
  • US8952369B2 patent drawing

AI summary

A light-emitting element includes an anode, a cathode, a luminescent layer disposed between the anode and the cathode and containing a host material, a first luminescence-assisting layer disposed in contact with the luminescent layer between the anode and the luminescent layer and containing a first luminescence-assisting material having characteristics the same as or similar to the host material, and a second luminescence-assisting layer disposed in contact with the luminescent layer between the cathode and the luminescent layer and containing a second luminescence-assisting material having characteristics the same as or similar to the host material. The luminescent layer and the first luminescence-assisting layer each contain a high-molecular-weight material.