Light-Emitting Particle-Polymer Composite for Display Stability

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Solution Overview

Problem

Current semiconductor nanocrystals used in display devices face challenges with stability, luminous efficacy, and color purity, limiting their application in optoelectronic devices.

Innovation Solution

A light emitting particle-polymer composite is developed, comprising a light emitting particle, a first monomer with at least two thiol groups, and a second monomer with unsaturated carbon-carbon bonds, which are polymerized to form a stable matrix for the nanocrystals, enhancing device efficiency and lifetime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If semiconductor nanocrystals are used in display devices, then color purity and quantum confinement effects are improved, but stability and lifetime are insufficient

Engineering Contradiction:
Improvecolor purityVSAvoidstability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent uses a composite polymer matrix system comprising a first polymer with carboxyl groups and a second polymer with hydroxyl groups to encapsulate semiconductor nanocrystals. This composite approach provides both stable encapsulation for improved lifetime and maintains the quantum confinement effects necessary for color purity in display applications.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The polymer matrix acts as an intermediary between the semiconductor nanocrystals and the external environment, protecting the nanocrystals from degradation while maintaining their optoelectronic properties. The functional groups (carboxyl and hydroxyl) on the polymer chains provide coordination sites that stabilize the nanocrystal surfaces.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Power

If semiconductor nanocrystals are used in display devices, then luminous efficacy is improved, but device lifetime is limited

Engineering Contradiction:
Improveluminous efficacyVSAvoiddevice lifetime
Core Design Contradiction:
PowerVSDuration of action of stationary object

Solution Approach 1:

The dual-polymer composite matrix provides enhanced protective capabilities compared to single-polymer systems, maintaining high luminous efficacy of the nanocrystals while extending device lifetime through superior encapsulation and environmental barrier properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces specific functional groups (carboxyl and hydroxyl) at localized positions on the polymer chains to provide targeted protection and stabilization at the nanocrystal-polymer interface, while the bulk polymer provides mechanical support and environmental barrier functions.

Inventive Principle:
Principle #3Local quality

3Reliability

If polymer matrices are used to encapsulate nanocrystals, then stability is improved, but manufacturing complexity increases

Engineering Contradiction:
ImprovestabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs preliminary surface modification of nanocrystals and pre-synthesis of functional polymers with specific groups before assembly. This preliminary preparation simplifies the final encapsulation process and improves stability without significantly increasing overall manufacturing complexity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The light emitting particle-polymer composite exhibits improved stability and efficiency, maintaining luminous performance over extended periods, thus addressing the limitations of existing semiconductor nanocrystals.

Implementation Method 1

a first monomer including at least two thiol groups, each located at a terminal end of the first monomer; and a second monomer including at least two unsaturated carbon-carbon bonds, each located at a terminal end of the second monomer

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentEP2588448B1Composition for light-emitting particle-polymer composite, light-emitting particle-polymer composite, and device including the light-emitting particle-polymer composite
Publication Date: 2017.10.18 SAMSUNG ELECTRONICS CO LTD
  • EP2588448B1 patent drawing
  • EP2588448B1 patent drawing
  • EP2588448B1 patent drawing

AI summary

A composition for manufacture of a light emitting particle-polymer composite, the composition including a light emitting particle, a first monomer including at least two thiol groups, each located at a terminal end of the first monomer, and a second monomer including at least two unsaturated carbon-carbon bonds, each located at a terminal end of the second monomer.