Liquid Fuel Synthesis Membrane Protection Using Heated Sweep Gas

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Solution Overview

Problem

The durability of the separation membrane in liquid fuel synthesis systems is compromised due to reduced pressure and increased relative humidity on the permeation side, especially in high temperature and high humidity environments, leading to potential decomposition.

Innovation Solution

The system maintains a higher temperature on the permeation side by using a sweep gas with controlled heating, suppressing the reduction in temperature and humidity on the permeation side of the separation membrane, thereby enhancing the durability of the membrane.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If water vapor is separated from the raw material gas to improve conversion efficiency, then conversion efficiency is improved, but durability of the separation membrane deteriorates due to high temperature and high humidity environment

Engineering Contradiction:
Improveconversion efficiencyVSAvoiddurability of separation membrane
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the temperature parameter on the permeation side by introducing heated sweep gas, raising it from a lower temperature to a higher temperature (e.g., 200-400°C). This parameter change reduces relative humidity while maintaining water vapor removal efficiency, thereby protecting the membrane from degradation in high-temperature, high-humidity conditions while preserving conversion efficiency improvement

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If temperature on permeation side is reduced to enhance water vapor permeation, then water vapor removal is improved, but relative humidity increases which reduces membrane durability

Engineering Contradiction:
Improvewater vapor permeationVSAvoiddurability of separation membrane
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

Instead of lowering temperature to enhance permeation, the patent changes multiple parameters simultaneously: it introduces sweep gas to increase water vapor partial pressure difference, and heats the sweep gas to raise temperature. This combination maintains high water vapor permeation while reducing relative humidity, avoiding membrane degradation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite approach combining sweep gas introduction with heating, creating a combined effect that achieves both high water vapor removal and low relative humidity, protecting the membrane while maintaining permeation efficiency

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively suppresses the reduction in durability of the separation membrane by maintaining high temperatures and reducing relative humidity, ensuring the membrane's longevity and efficiency in high humidity conditions.

Implementation Method 1

a separation membrane permeable to water vapor which is a by-product of the conversion reaction

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 2

a heating unit configured to heat the sweep gas

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentEP4166530B1Liquid fuel synthesis system
Publication Date: 2025.08.06 NGK INSULATORS LTD
  • EP4166530B1 patent drawingFigure 1
  • EP4166530B1 patent drawingFigure 2
  • EP4166530B1 patent drawingFigure 3

AI summary

Aliquid fuel synthesis system (100) includes a liquid fuel synthesis portion (110) and a sweep gas supply unit (130). The liquid fuel synthesis portion (110) includes a separation membrane (3) permeable to water vapor which is a by-product of a conversion reaction of a raw material gas containing hydrogen and carbon oxide to a liquid fuel. The sweep gas supply unit (130) supplies the liquid fuel synthesis portion (110) with a sweep gas for sweeping the water vapor permeating through the separation membrane (3). A temperature (Tp 1) of the sweep gas flowing into a permeation side space (110B) and a temperature (Tp2) of a second outflow gas flowing out of the permeation side space (110B) are each higher than a lower temperature of a temperature (Tq1) of the raw material gas flowing into a non-permeation side space (110A) and a temperature (Tq2) of a first outflow gas flowing out of the non-permeation side space (110A).