Lithographic Printing Plate Precursor with Color Developing System

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Solution Overview

Problem

On-machine development-type lithographic printing plate precursors face challenges in image visibility and contamination issues during laser exposure and ink/water usage, with existing solutions either impairing radical polymerization or causing contamination of non-image areas.

Innovation Solution

A thermal fusion-type lithographic printing plate precursor with an image-recording layer containing a color developing system that achieves Δa/Δb ≥ 0.6 hue change and 70% thermoplastic polymer particles, allowing excellent visibility and suppressing ablation and contamination during infrared laser exposure and on-machine development.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a color developing system is added to improve image visibility, then visibility is improved, but the system complexity increases

Engineering Contradiction:
Improveimage visibilityVSAvoidsystem complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent applies color changing compounds that undergo hue changes (Δa/Δb ≥ 0.6) upon infrared laser irradiation. This allows the exposed areas to change color, providing visual feedback for image verification without requiring additional complex detection systems. The color change itself serves as the measurement mechanism.

Inventive Principle:
Principle #32Color changes

2Productivity

If infrared laser exposure is used for on-machine development, then productivity is improved, but ablation and contamination occur

Engineering Contradiction:
Improveplate-making efficiencyVSAvoidablation and contamination
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the infrared laser wavelength parameters to match the absorption characteristics of the infrared absorber compound. By selecting specific wavelength ranges and exposure energy densities, the system achieves sufficient heating for color development while minimizing ablation and contamination. The parameter optimization balances productivity with harmful effect reduction.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces an infrared absorber compound as an intermediary that converts infrared laser energy into localized heat. This intermediary enables indirect heating, allowing the use of infrared lasers for on-machine development while controlling the heating process to minimize ablation and contamination through the color developing system.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If thermoplastic polymer particles are used for thermal fusion, then on-machine development is enabled, but contamination of dampening water occurs

Engineering Contradiction:
Improveon-machine development capabilityVSAvoiddampening water contamination
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the glass transition temperature and molecular weight of thermoplastic polymer particles to achieve melting and fusion at controlled temperatures during on-machine development. By carefully selecting polymer parameters, the system enables effective image formation while minimizing polymer degradation and contamination of dampening water.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides excellent image visibility, suppresses ablation during laser exposure, and minimizes contamination of dampening water or printing ink, enhancing the on-machine development process.

Implementation Method 1

a color developing system in which a hue change generated by infrared laser exposure is Δa/Δb≥0.6

Methodology Applied
Scientific EffectPhotochromism: Photochromism

Implementation Method 2

containing an infrared absorber, a polymerization initiator, and a polymerizable compound

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Implementation Method 3

a thermal fusion-type image-recording layer containing an infrared absorber and a thermoplastic polymer particle

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 4

image exposure is carried out by, for example, scanning and exposing a lithographic printing plate precursor using a laser or a laser diode

Methodology Applied
Scientific EffectLaser: Laser

Data Source

PatentEP3508349B1Lithographic printing plate precursor and plate-making method using same
Publication Date: 2021.12.15 FUJIFILM CORP
  • EP3508349B1 patent drawing
  • EP3508349B1 patent drawing
  • EP3508349B1 patent drawing

AI summary

Provided are a thermal fusion-type lithographic printing plate precursor in which the visibility is excellent, ablation during laser exposure is suppressed, and the contamination of dampening water and printing ink during on-machine development is suppressed by a lithographic printing plate precursor having a support and an image-recording layer, in which the image-recording layer is capable of forming an image by infrared laser exposure, a non-exposed portion of the image-recording layer is removable by at least one of dampening water and printing ink on a printer, and the image-recording layer contains (1) a color developing system in which a hue change generated by infrared laser exposure is Δa/Δb≥0.6 and (2) 70% by mass or more of a thermoplastic polymer particle with respect to a solid content of the image-recording layer and a plate-making method in which the thermal fusion-type lithographic printing plate precursor is used.