Multibeam Interference Lithography Exposure Time Control

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Solution Overview

Problem

Current methods for forming three-dimensional photonic crystals through multibeam interference lithography lack control over the proportion of voids and solid volumes, which is crucial for achieving desired structural properties and applications such as optical switching and catalysis.

Innovation Solution

The method involves using non-equal intensity laser beams and varying irradiation time to control the dosage of light in multibeam interference lithography, allowing for precise control of the proportion of void and solid volumes in the three-dimensional photonic crystal templates without altering the photoresist composition, beam orientation, or wavelength, thereby enabling the formation of templates with tailored density distributions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If multibeam interference lithography is used to form three-dimensional photonic crystals, then pattern coherence and patterning speed are improved, but control over the proportion of voids and solid volumes is lost

Engineering Contradiction:
Improvepatterning speedVSAvoidcontrol over void and solid volume proportion
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by varying the exposure time of the photoresist to light during multibeam interference lithography. By adjusting the exposure time parameter, the degree of polymerization and crosslinking is controlled, which directly influences the proportion of voids and solid volumes in the resulting photonic crystal structure. This allows precise control over the density distribution while maintaining the high patterning speed of multibeam interference lithography.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If longer irradiation time is used to increase light dosage, then the proportion of solid volume increases, but the pattern formation precision may be compromised

Engineering Contradiction:
Improveproportion of solid volumeVSAvoidpattern formation precision
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent employs dynamics by making the exposure time a variable parameter that can be dynamically adjusted to achieve the desired proportion of solid and void volumes. Rather than using a fixed exposure time, the method allows optimization of the irradiation duration based on the specific requirements of the photonic crystal structure being formed, thereby maintaining pattern formation precision while controlling the quantity of solid material.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent implements feedback control through the relationship between exposure time and the resulting polymerization degree. By monitoring and adjusting the exposure time based on the desired outcome, the process achieves precise control over solid volume proportion while maintaining pattern integrity. The feedback mechanism ensures that the light dosage is optimized to achieve the target density distribution without compromising pattern formation precision.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the precise control of void and solid volume ratios in three-dimensional photonic crystal templates, enhancing their structural properties and enabling their use in applications like supported catalysis and heat transfer materials by ensuring consistent pattern formation and defect-free structures.

Implementation Method 1

four laser beams can be used to generate a three-dimensional periodicity resulting from the constructive and destructive interference patterns that define the void pattern

Methodology Applied
Scientific EffectInterference: Interference

Implementation Method 2

the photolyzed mass is developed by baking to a temperature where polymerization and crosslinking of the photoresist occurs

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS11914304B2Controlling porosity of an interference lithography process by fine tuning exposure time
Publication Date: 2024.02.27 TOYOTA JIDOSHA KK
  • US11914304B2 patent drawing
  • US11914304B2 patent drawing
  • US11914304B2 patent drawing

AI summary

A method to control the density of a three-dimensional photonic crystal template involves changing the irradiation time from at least four laser beams to yield a periodic percolating matrix of mass and voids free of condensed matter from a photoresist composition. The photoresist composition includes a photoinitiator at a concentration where the dose or irradiation is controlled by the irradiation time and is less than the irradiation time that would convert all photoinitiator to initiating species such that the density of the three-dimensional photonic crystal template differs for different irradiation times. A deposition of reflecting or absorbing particles can be patterned on the surface of the photoresist composition to form a template with varying densities above different areas of the substrate.