Mask Layer Pre-Treatment for Etching Line Edge Roughness

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Solution Overview

Problem

The existing dry plasma etching processes using ballistic electron beams often result in line edge roughness (LER) and pattern abnormalities in the mask layer, which are transferred to the underlying layers, leading to reduced manufacturing yields and poor device performance due to initial exposure to atomic halogen species and energetic electrons.

Innovation Solution

Treating the mask layer with a pre-etching electron beam in the absence of atomic halogen species, followed by exposure to an oxygen-containing, halogen-containing, or noble gas plasma, or forming a protective layer to alter the mask layer and reduce LER, and then using a ballistic electron beam and etching plasma to transfer the pattern to the thin film.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the mask layer is exposed to atomic halogen species and energetic electrons during the etching process, then the etching process can proceed effectively, but line edge roughness and pattern abnormalities occur in the mask layer

Engineering Contradiction:
Improveetching efficiencyVSAvoidline edge roughness
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by treating the mask layer with a pre-etching electron beam before the actual etching process. This pre-treatment modifies the mask layer properties in advance, making it more resistant to the harmful effects of atomic halogen species and energetic electrons during etching, thereby preventing line edge roughness while maintaining etching efficiency

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces an intermediary substance (oxygen-containing, halogen-containing, or noble gas plasma) that acts as a protective layer between the mask layer and the harmful etching environment. This intermediary layer shields the mask from direct exposure to atomic halogen species and energetic electrons, reducing line edge roughness while allowing the etching process to proceed

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If the mask layer is treated to reduce line edge roughness, then manufacturing yield improves, but the etching process may be compromised

Engineering Contradiction:
Improvepattern qualityVSAvoidetching performance
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent applies parameter changes by carefully controlling the energy, duration, and intensity of the pre-etching electron beam treatment. By optimizing these parameters, the mask layer is modified sufficiently to reduce line edge roughness while maintaining its etch resistance and ensuring the etching process can still proceed effectively

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The pre-etching treatment is designed to prepare the mask layer in advance with optimal properties for the subsequent etching process, ensuring both high pattern quality and maintained etching performance through careful parameter selection

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed method effectively reduces line edge roughness and pattern abnormalities, enhancing etch selectivity and manufacturing yields by altering the mask layer to be more resilient to the etching process without compromising the etching process's benefits.

Implementation Method 1

treating the mask layer with a pre-etching electron beam in the absence of an atomic halogen specie

Methodology Applied
Scientific EffectElectron beam: Electron Beam

Implementation Method 2

etching the thin film in a plasma processing system

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 3

coupling direct current (DC) power to an electrode in the plasma processing system to form an etching electron beam to assist the etching plasma

Methodology Applied
Scientific EffectBallistic electron beam: Electron Beam

Data Source

PatentUS7572386B2Method of treating a mask layer prior to performing an etching process
Publication Date: 2009.08.11 TOKYO ELECTRON LTD
  • US7572386B2 patent drawing
  • US7572386B2 patent drawing
  • US7572386B2 patent drawing

AI summary

A method of pre-treating a mask layer prior to etching an underlying thin film is described. A thin film, such as a dielectric film, is etched using plasma that is enhanced with a ballistic electron beam. In order to reduce the loss of pattern definition, such as line edge roughness effects, the mask layer is treated with an electron beam in the absence of an atomic halogen specie prior to proceeding with the etching process.