Membrane-less Electrolyzer Fluidic Gas Separation

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Solution Overview

Problem

Conventional electrolyzers using ion exchange membranes, such as Nafion, are expensive, have limited lifetimes, and are restricted to acidic pH conditions, limiting the use of earth-abundant catalysts and increasing the production cost of hydrogen gas, which is a clean but costly fuel.

Innovation Solution

A membrane-less electrolyzer design that operates without ion exchange membranes, using electrical insulation and gas impermeable flow plates, allowing for continuous operation across the pH scale and reducing ionic resistance, with gas separation controlled by fluid dynamics to minimize crossover.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If ion exchange membranes (Nafion) are used in electrolyzers, then gas separation and ion conductivity are improved, but production cost and device complexity increase

Engineering Contradiction:
Improvegas separationVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent removes the ion exchange membrane from the electrolyzer system entirely. The flow plate with integrated flow channels performs both electrical insulation and gas separation functions that were previously handled by separate membranes, thereby eliminating the membrane component and reducing device complexity while maintaining gas separation capability.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent combines multiple functions into the flow plate: electrical insulation, gas separation, and fluid distribution. By integrating these functions into a single component rather than using separate membranes for each function, the overall device complexity is reduced while maintaining the necessary performance characteristics.

Inventive Principle:
Principle #5Merging (Combining)

2Reliability

If ion exchange membranes (Nafion) are used in electrolyzers, then gas separation is improved, but production cost increases

Engineering Contradiction:
Improvegas separationVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent eliminates the expensive ion exchange membrane from the system. The flow plate made from conventional materials performs the gas separation function without requiring costly membrane materials, significantly reducing production costs while maintaining adequate gas separation performance.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses inexpensive flow plate materials instead of expensive membranes. While the flow plate may have limited lifespan compared to high-performance membranes, the dramatic cost reduction makes this a economically viable alternative for hydrogen production applications.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If ion exchange membranes are used in electrolyzers, then ion conductivity is improved, but ionic resistance increases

Engineering Contradiction:
Improveion conductivityVSAvoidionic resistance
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent replaces the membrane-based ion conduction mechanism with a direct liquid electrolyte path between electrodes. This eliminates the ionic resistance associated with membrane materials and their interfaces, allowing ions to move freely through the liquid electrolyte with minimal resistance, thereby reducing energy losses.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Ease of manufacture

If membrane-less design is used, then production cost and ionic resistance are reduced, but gas crossover increases

Engineering Contradiction:
Improveproduction costVSAvoidgas crossover
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent introduces the flow plate with integrated flow channels as an intermediary structure between the electrodes. This flow plate provides electrical insulation and creates physical separation zones that guide gas bubbles to appropriate outlets, preventing direct mixing of hydrogen and oxygen gases while maintaining the membrane-less design benefits.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The membrane-less electrolyzer achieves efficient hydrogen production with low gas crossover, extended lifespan, and reduced costs, enabling competitive hydrogen fuel production and facilitating the deployment of renewable energy sources.

Implementation Method 1

electrolysis of a fluid to decompose the fluid into at least a first and a second gas

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

Electrical insulation and gas impermeability of the flow plates are the only material requirements

Methodology Applied
Scientific EffectElectrical insulation: Dielectric

Implementation Method 3

Electrical insulation and gas impermeability of the flow plates are the only material requirements

Methodology Applied
Scientific EffectGas impermeability: Permeation

Data Source

PatentUS10907262B2Membrane-less electrolyzer
Publication Date: 2021.02.02 ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)
  • US10907262B2 patent drawing
  • US10907262B2 patent drawing
  • US10907262B2 patent drawing

AI summary

The present invention concerns a membrane-less electrolyzer comprising a fluidic channel for receiving an electrolyte fluid; a first electrode and a second electrode located inside the fluidic channel, the first and second electrode permitting to extract a first gas and a second gas inside the fluidic channel from the electrolyte fluid, the first electrode and second electrode being separated by solely a surrounding fluid in the fluidic channel or the electrolyte; and a first fluidic transport channel for transporting the first gas to a first outlet and a second fluidic transport channel for transporting the second gas to a second outlet.