Membrane Separator for Aromatic Hydrocarbon Purification

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Solution Overview

Problem

Conventional distillation processes are inefficient and costly for producing high-purity aromatic hydrocarbons like benzene, toluene, and xylenes due to contamination issues in solvent streams, leading to frequent maintenance and reduced equipment lifespan in petrochemical plants.

Innovation Solution

A membrane separator is used to purify lean-solvent streams by removing heavy components and contaminants, allowing for the efficient separation of aromatic and non-aromatic hydrocarbons, thereby extending equipment life and reducing operational costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional distillation processes are used to separate aromatic hydrocarbons from mixture feed, then separation can be achieved, but the process is inefficient and costly due to contamination issues in solvent streams

Engineering Contradiction:
Improveseparation efficiencyVSAvoidsolvent stream contamination
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent extracts and removes contaminants (heavy components) from the solvent stream using a membrane separator before recycling the solvent back to the extraction column. This prevents contamination accumulation that would otherwise reduce separation efficiency and increase operational costs.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The membrane separator acts as an intermediary device between the extraction column and solvent recycle system. It selectively separates contaminants from the solvent stream without requiring chemical reactions or complex processing, enabling clean solvent recycling and maintaining high separation efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If solvent-assisted separation processes are used to produce high-purity aromatic hydrocarbons, then purity can be improved, but contaminants accumulate in the recycled solvent stream over time

Engineering Contradiction:
Improvearomatic hydrocarbon purityVSAvoidcontaminant accumulation
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful effect of contaminant accumulation into a benefit by using the membrane separator to selectively remove heavy components. The separator exploits the size and polarity differences between contaminants and solvent molecules to achieve automatic purification, turning a problematic accumulation issue into an effective cleaning mechanism.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The membrane separator changes the physical parameters of the solvent stream by selectively removing contaminants based on molecular size and polarity. This parameter-based separation maintains solvent purity without requiring chemical regeneration processes, enabling continuous high-purity aromatic hydrocarbon production.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If solvent regeneration units and stream purification units are added to reduce contaminants, then solvent quality can be maintained, but capital expenditure and operational costs increase significantly

Engineering Contradiction:
Improvesolvent stream qualityVSAvoidsystem complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical and chemical regeneration systems (steam stripping columns, sorbent beds) with a simpler membrane separation system. The membrane separator uses selective permeability based on molecular characteristics rather than requiring thermal energy input or chemical reactions, significantly reducing device complexity while maintaining solvent quality.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent employs a thin-film membrane separator that provides efficient contaminant removal with minimal pressure drop and energy consumption. The membrane's selective permeability allows clean solvent to pass through while retaining contaminants, achieving effective purification with a simple, compact structure that reduces both capital and operational costs.

Inventive Principle:
Principle #30Flexible shells and thin films

4Reliability

If frequent maintenance and solvent regeneration are performed to handle contamination, then equipment reliability can be maintained, but equipment lifespan is reduced and operational continuity is disrupted

Engineering Contradiction:
Improveequipment reliabilityVSAvoidequipment lifespan
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The membrane separator performs preliminary cleaning of the solvent stream before it is recycled to the extraction column. By removing contaminants proactively rather than waiting for accumulation problems to develop, the system prevents equipment fouling and corrosion, extending equipment lifespan while maintaining continuous operation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The membrane separator enables continuous solvent purification without requiring shutdowns for maintenance or regeneration. The separator operates continuously alongside the extraction process, maintaining constant solvent quality and equipment reliability while eliminating disruptive maintenance cycles and extending equipment service life.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The membrane separator effectively purifies lean-solvent streams, reducing contamination and energy consumption, and enhances the production of high-purity aromatic hydrocarbons by selectively permeating polar solvents over heavy components, improving the overall efficiency and longevity of the separation process.

Implementation Method 1

the membrane is more permeable to the polar solvent than to the heavy components

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 2

A membrane separator is used to purify lean-solvent streams by removing heavy components and contaminants

Methodology Applied
Scientific EffectSelective separation: Semipermeable Membrane

Data Source

PatentUS12145908B2Hydrocarbon extraction and/or separation processes utilizing a membrane separator
Publication Date: 2024.11.19 EXXONMOBIL ENG & TECH CO
  • US12145908B2 patent drawing
  • US12145908B2 patent drawing
  • US12145908B2 patent drawing

AI summary

A membrane separator comprising a membrane is used to separate various streams in processes for separating aromatic hydrocarbons from non-aromatic hydrocarbons. Such streams can be a lean-solvent stream, a rich-solvent stream, or a hydrocarbon stream comprising both aromatic and non-aromatic hydrocarbons. The membrane separator is advantageously used in combination with an extraction sub-system including a liquid-liquid distillation column and/or an extraction distillation column.