Metal Ball Alpha Dose Reduction via Impurity Evaporation

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Solution Overview

Problem

High-density mounting of electronic components leads to software errors due to α rays from radioactive impurities in solder alloys and metal balls, which also results in reduced sphericity and increased costs when using high-purity materials.

Innovation Solution

A method of producing metal balls with a low α dose by heating metal materials with reduced U and Th content to evaporate impurities like 210Po, maintaining high sphericity through controlled heating and annealing, and incorporating Pb or Bi to enhance sphericity without increasing α dose.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If high purity metal material is used to produce metal balls, then alpha dose is reduced, but cost increases and sphericity decreases

Engineering Contradiction:
Improvealpha doseVSAvoidcost
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The invention extracts and removes specific radioactive impurities (U, Th, Po) from the metal material through selective purification processes. By targeting and removing only the harmful radioactive elements rather than requiring complete purification to extremely high purity levels, the method achieves low alpha dose (0.0200 cph/cm² or less) while avoiding the excessive costs and sphericity degradation associated with using ultra-high purity metal materials.

Inventive Principle:
Principle #2Taking out (Extraction)

2Object-affected harmful factors

If high purity metal material is used to produce metal balls, then alpha dose is reduced, but sphericity decreases

Engineering Contradiction:
Improvealpha doseVSAvoidsphericity
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The invention selectively removes radioactive impurities through targeted purification processes rather than relying on ultra-high purity materials. This extraction approach achieves the required low alpha dose while preserving the sphericity of metal balls, as the purification process does not compromise the spherical shape formation during the ball-making process.

Inventive Principle:
Principle #2Taking out (Extraction)

3Productivity

If solder balls are used for high-density mounting, then mounting density increases, but software errors occur due to alpha radiation

Engineering Contradiction:
Improvemounting densityVSAvoidsoftware errors
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The invention converts the potentially harmful alpha radiation issue into a benefit by identifying and removing the specific radioactive impurities (U, Th, Po) that cause software errors. This allows the continued use of metal balls for high-density mounting applications while eliminating the software error problem, effectively turning a harmful factor into an opportunity for improved reliability.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Productivity

If metal balls with very small diameter are used for high-density mounting, then mounting density increases, but metal balls are crushed by self-weight

Engineering Contradiction:
Improvemounting densityVSAvoidmechanical strength
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The invention changes the material parameters of the metal balls by controlling the purity level and specific impurity content (U ≤5 ppb, Th ≤5 ppb). This parameter optimization allows the metal balls to maintain sufficient mechanical strength to support their own weight in high-density mounting configurations while keeping the diameter small enough to achieve high mounting density.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces metal balls with an α dose of 0.0200 cph/cm2 or less and sphericity of 0.90 or more, preventing software errors and maintaining high-density mounting capabilities while reducing production costs.

Implementation Method 1

heating the pure metal at a heating temperature which is set to be higher than a boiling point of an impurity to be removed

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

heating the pure metal at a heating temperature which is set to be higher than a melting point of the pure metal

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS10150185B2Method for producing metal ball, joining material, and metal ball
Publication Date: 2018.12.11 SENJU METAL IND CO LTD
  • US10150185B2 patent drawing
  • US10150185B2 patent drawing

AI summary

Produced is a metal ball which suppresses an emitted α dose. Contained are the steps of melting a pure metal by heating the pure metal at a temperature which is higher than a boiling point of an impurity to be removed, higher than a melting point of the pure metal, and lower than a boiling point of the pure metal, the pure metal containing a U content of 5 ppb or less, a Th content of 5 ppb or less, purity of 99.9% or more and 99.995% or less, and a Pb or Bi content or a total content of Pb and Bi of 1 ppm or more, and the pure metal having the boiling point higher than the boiling point at atmospheric pressure of the impurity to be removed; and sphering the molten pure metal in a ball.