Melamine-Formaldehyde Foam Hollow Microsphere Fixation

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Solution Overview

Problem

Melamine-formaldehyde foams incorporating high loadings of hollow microspheres face challenges in maintaining good mechanical properties and effective fixation of these microspheres within the foam structure, often requiring additional production steps and processes.

Innovation Solution

The development of melamine-formaldehyde foams with hollow microspheres having a median particle diameter of 260 μm to 490 μm, which are preferentially embedded into the open-cell pores of the foam structure during production, ensuring better fixation and mechanical properties without additional process steps.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hollow microspheres with smaller particle diameter (0.5-100 μm or 70-250 μm) are incorporated into melamine-formaldehyde foam, then the foam can achieve functional properties (thermal insulation, scent release, hydrophobicity), but the mechanical properties of the foam are impaired and fixation becomes difficult at high loadings

Engineering Contradiction:
Improvefunctional properties of foamVSAvoidmechanical properties of foam
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies parameter changes by optimizing the particle diameter of hollow microspheres to a specific range (260-490 μm). This parameter adjustment resolves the contradiction by finding an optimal size that provides sufficient functional properties while maintaining good mechanical properties and fixation at high loadings, avoiding the impairment caused by smaller particles

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If high loadings of hollow microspheres are incorporated into the foam, then the functional content (active substances, heat storage media) increases, but the fixation of hollow microspheres becomes difficult and mechanical properties deteriorate

Engineering Contradiction:
Improvehollow microsphere contentVSAvoidfixation of hollow microspheres
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent resolves this contradiction by changing the particle diameter parameter to 260-490 μm, which enables effective fixation of hollow microspheres even at high loadings (5-50% by weight). This size range provides optimal balance between quantity incorporation and fixation quality, preventing the deterioration seen with smaller particles

Inventive Principle:
Principle #35Parameter changes

3Reliability

If hollow microspheres are incorporated into nodal points or struts of foam structure, then functional properties are achieved, but additional process steps are required and fixation difficulty increases with loading

Engineering Contradiction:
Improvefunctional propertiesVSAvoidproduction process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts the requirement for additional impregnation process steps by incorporating hollow microspheres directly into the foam during the foaming operation itself. The optimized particle size (260-490 μm) allows microspheres to be integrated into the foam matrix without requiring separate fixation steps, simplifying the production process while maintaining functional properties

Inventive Principle:
Principle #2Taking out (Extraction)

Data Source

PatentUS9353232B2Melamine-formaldehyde foams comprising hollow microspheres
Publication Date: 2016.05.31 BASF SE

AI summary

The present invention relates to melamine-formaldehyde foams comprising hollow microspheres wherein said hollow microspheres have a median particle diameter (D50, volume averaged, Malvern, Fraunhofer diffraction) in the range from 260 μm to 490 μm, and also processes for producing these melamine-formaldehyde foams and their uses.