Microcalorimeter X-ray Spectrometer Array Design

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Solution Overview

Problem

Microcalorimeter-type EDS systems face limitations in throughput and energy resolution, making high-resolution x-ray mapping of samples inefficient due to low count rates and limited x-ray collection, which hinders the creation of two- or three-dimensional maps in a reasonable time.

Innovation Solution

The system employs a wide-angle x-ray optic for increased x-ray collection, multiple detectors to enhance count rates, and a neutron transmutation doped temperature measurement element for improved resolution, along with a dual beam system for electron and ion beam analysis, enabling high-resolution x-ray mapping.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a microcalorimeter detector is used to achieve superior energy resolution (less than 5 eV at 6 keV), then the ability to differentiate closely spaced x-ray peaks is improved, but the maximum count rate deteriorates to less than 500 x-rays per second

Engineering Contradiction:
Improveenergy resolutionVSAvoidmaximum count rate
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The invention divides the detector system into multiple independent microcalorimeter detectors arranged in an array. Each detector element can independently detect x-rays, allowing the system to process multiple x-rays simultaneously through parallel detection channels. This segmentation enables the system to achieve a maximum count rate significantly higher than a single detector while maintaining the superior energy resolution of microcalorimetry.

Inventive Principle:
Principle #1Segmentation

2Ease of manufacture

If x-ray optics with a narrow acceptance angle (two to three degrees) are used, then the system maintains simplicity and ease of manufacture, but the fraction of emitted x-rays collected by the detector deteriorates, reducing throughput

Engineering Contradiction:
Improvex-ray optic fabricationVSAvoidx-ray collection efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The invention transitions from a single-point detection geometry to a two-dimensional array of detector elements. This dimensional change allows the system to collect x-rays over a much broader solid angle while maintaining a relatively simple optic design. The array configuration effectively captures x-rays emitted in multiple directions simultaneously, dramatically improving collection efficiency without requiring complex multi-focal optics.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Device complexity

If a single detector is used to maintain system simplicity, then the device complexity is reduced, but the ability to process large numbers of x-rays per second deteriorates due to pulse pileup limitations

Engineering Contradiction:
Improvedetector system configurationVSAvoidcount rate
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The detector system is segmented into multiple independent detection elements arranged in an array. Each element operates as an independent detection channel with its own signal processing path. This segmentation eliminates pulse pileup limitations by distributing the count rate across multiple channels, allowing the system to process large numbers of x-rays per second simultaneously while maintaining relatively simple individual detector designs.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration allows for practical high spatial and energy resolution x-ray mapping, overcoming the limitations of prior systems by increasing the fraction of collected x-rays and improving count rates, enabling efficient two- or three-dimensional mapping.

Implementation Method 1

an x-ray is absorbed by a detector and the x-ray energy is determined by measuring an increase in temperature of the detector, the increase being proportional to the energy of the absorbed x-ray

Methodology Applied
Scientific EffectX-ray absorption and calorimetry: Absorption (EM radiation)

Implementation Method 2

the x-ray energy is determined by measuring an increase in temperature of the detector

Methodology Applied
Scientific EffectCalorimetry: Calorimetry

Implementation Method 3

The temperature measuring device employed by most commercial systems includes a transition edge sensor, which includes a layer of non-superconducting material and a layer of superconducting material maintained near its transition temperature, that is, the temperature at which it stops superconducting. An electrical current through the transition edge sensor changes as the temperature of the sensor changes.

Methodology Applied
Scientific EffectTransition edge sensor effect:

Implementation Method 4

The change in electrical current is typically amplified using a superconducting quantum interference device (SQUID).

Methodology Applied
Scientific EffectSuperconducting quantum interference device (SQUID):

Implementation Method 5

X-ray optics are typically either made from glass capillaries or from a thin metallic film... an x-ray optic has a large acceptance angle, and a large collection solid angle

Methodology Applied
Scientific EffectX-ray optics:

Data Source

PatentEP2284524B1Microcalorimetry for X-ray spectroscopy
Publication Date: 2014.01.15 FEI CO
  • EP2284524B1 patent drawingFigure 1A~2
  • EP2284524B1 patent drawingFigure 3
  • EP2284524B1 patent drawingFigure 4

AI summary

An improved microcalorimeter-type energy dispersive x-ray spectrometer provides sufficient energy resolution and throughput for practical high spatial resolution x-ray mapping of a sample at low electron beam energies. When used with a dual beam system that provides the capability to etch a layer from the sample, the system can be used for three-dimensional x-ray mapping. A preferred system uses an x-ray optic having a wide-angle opening to increase the fraction of x-rays leaving the sample that impinge on the detector and multiple detectors to avoid pulse pile up.