Mixed Fleet Lubricant Additive Package Design

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Solution Overview

Problem

Current lubricants designed for spark ignition passenger car engines do not meet the friction requirements for compression ignition heavy duty applications, and vice versa, due to differing performance standards, leading to inadequate performance in mixed fleet use.

Innovation Solution

A lubricating composition that includes a detergent system providing calcium and magnesium from sulfonates or phenates, and an antiwear and friction system with metal dialkyl dithiophosphates derived from primary and secondary alcohols, optimized to meet both LSPI performance standards for spark ignition engines and friction requirements for compression ignition heavy duty engines, with specific ratios and concentrations of magnesium, phosphorus, and zinc.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If lubricants are tailored to meet specific performance requirements for one application (spark ignition or compression ignition), then performance for that application is improved, but performance for the other application deteriorates

Engineering Contradiction:
Improveperformance complianceVSAvoidapplication compatibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent develops a universal lubricant composition that simultaneously meets the performance requirements of both spark ignition passenger car engines (API SP standards including LSPI protection) and compression ignition heavy duty engines (API CK-4 standards including friction control). This is achieved through a carefully balanced additive package containing detergents (calcium phenate, magnesium sulfonate), antiwear agents (ZDDP with specific phosphorus and zinc levels), and friction modifiers that function effectively across both engine types, eliminating the need for separate lubricant formulations.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If phosphorus levels are reduced to meet LSPI performance standards, then spark ignition engine performance is improved, but antiwear protection for compression ignition engines deteriorates

Engineering Contradiction:
ImproveLSPI protectionVSAvoidantiwear protection
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent optimizes the phosphorus content parameter to a specific range (800-1200 ppm) that simultaneously provides adequate LSPI protection for spark ignition engines and sufficient antiwear protection for compression ignition engines. This parameter optimization is achieved through careful selection of ZDDP concentration and alkyl group composition (ratio of primary to secondary alcohol derivatives), creating a balanced formulation where phosphorus levels are controlled to prevent LSPI while maintaining film strength for heavy duty applications.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If zinc levels are reduced to meet emission standards, then environmental compliance is improved, but friction control for heavy duty engines deteriorates

Engineering Contradiction:
Improveemission complianceVSAvoidfriction
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent creates a composite additive system that combines multiple friction control mechanisms to replace the traditional high-zinc ZDDP approach. The formulation integrates ZDDP with controlled zinc levels (800-1000 ppm) alongside magnesium sulfonate detergents and other antiwear agents that collectively provide the necessary friction control for heavy duty engines while meeting emission standards. This composite approach distributes the friction protection function across multiple additives rather than relying solely on zinc.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentEP4202023B1Mixed fleet capable lubricating compositions
Publication Date: 2024.05.15 AFTON CHEMICAL CORPORATION
  • EP4202023B1 patent drawing
  • EP4202023B1 patent drawing
  • EP4202023B1 patent drawing

AI summary

This disclosure describes lubricating additives and lubricants including such additives suitable for and/or configured for mixed fleet use and, for instance, additives and lubricants that satisfy performance standards for typical spark ignition passenger car lubricants as well as performance standards for lubricants suitable for typical compression ignition heavy duty engine applications.