Multilayer Ceramic Capacitor Sn Plating Solder Bursting

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Solution Overview

Problem

Multilayer ceramic capacitors with thermosetting resin outer electrodes face issues with solder bursting due to moisture absorption and decomposition during high-temperature soldering, leading to defects such as chip detachment and reduced reliability in severe environments.

Innovation Solution

The capacitors incorporate a Sn plating layer directly on the resin electrode layer, allowing for gas release paths and reducing the need for a Ni plating layer, which helps in preventing solder bursting by controlling the Lf/La ratio and maintaining a strong fixing force with the substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a thermosetting resin layer is used for outer electrodes to prevent cracks in severe environments, then crack resistance is improved, but moisture absorption increases and solder bursting occurs

Engineering Contradiction:
Improvecrack resistanceVSAvoidsolder bursting resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The outer electrode is segmented into multiple functional layers: a resin electrode layer containing thermosetting resin for crack resistance, a Ni plating layer for moisture barrier and adhesion, and a Sn plating layer for soldering. Each layer addresses specific requirements without compromising overall reliability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The outer electrode uses a composite structure combining organic thermosetting resin with inorganic metal plating layers. This composite approach leverages the crack-resistant properties of the resin while the metal layers provide moisture barrier and soldering functionality, resolving the contradiction between mechanical strength and reliability.

Inventive Principle:
Principle #40Composite materials

2Reliability

If a Ni plating layer is added to prevent solder bursting, then sealing properties are improved, but device complexity and manufacturing cost increase

Engineering Contradiction:
Improvesealing propertiesVSAvoidelectrode structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The Ni plating layer serves multiple functions simultaneously: it acts as a moisture barrier to prevent solder bursting, provides adhesion between the resin layer and Sn plating layer, and enables proper soldering. This multi-functionality justifies the additional layer by consolidating multiple requirements into a single component.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration effectively reduces solder bursting and ensures a strong fixing force between the substrate and the capacitor, enhancing reliability and cost-effectiveness by eliminating the need for a Ni plating layer.

Implementation Method 1

moisture adsorbed to a resin in the resin electrode layer and resin-decomposed components are vaporized by heating performed when a multilayer ceramic capacitor is mounted on a substrate by reflow soldering

Methodology Applied
Scientific EffectVaporization: Evaporation

Implementation Method 2

the multilayer ceramic capacitor containing such a thermosetting resin tends to adsorb moisture because the thermosetting resin itself has hygroscopicity

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

such a resin is decomposed when exposed to a high temperature of about 250° C. in lead-free soldering (LF soldering)

Methodology Applied
Scientific EffectThermal decomposition: Decomposition (biological)

Data Source

PatentUS10665392B2Multilayer ceramic capacitor
Publication Date: 2020.05.26 MURATA MFG CO LTD
  • US10665392B2 patent drawing
  • US10665392B2 patent drawing
  • US10665392B2 patent drawing

AI summary

A multilayer ceramic capacitor includes a multilayer body including dielectric layers, inner electrodes and outer electrodes that are connected to the inner electrodes and disposed on a first end surface and a second end surface of the multilayer body. The outer electrodes each include a resin electrode layer containing a thermosetting resin and a metal component and a plating layer in contact with the resin electrode layer. The metal component of the resin electrode layer contains Ni. The plating layer is a Sn plating layer.