Monocrystalline Silicon Layer Formation for Semiconductor Memory

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Solution Overview

Problem

Conventional semiconductor memory devices face limitations in miniaturization due to the short channel effect, leading to decreased on-off ratios and unstable transistor operation, especially when channel lengths are 50 nm or less, and challenges in forming large-area silicon layers with good crystallinity on insulating films.

Innovation Solution

A method involving the formation of monocrystalline silicon layers on insulating films using solid-phase-epitaxial growth, followed by oxidation and CMP techniques to achieve ultrathin-film SOI-structure memory cells with improved crystallinity and reduced cell-to-cell variations, thereby suppressing the short channel effect.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the channel length is miniaturized to 50 nm or less, then the integration density is improved, but the on-off ratio decreases due to short channel effect

Engineering Contradiction:
Improveintegration densityVSAvoidon-off ratio
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the physical state of the silicon layer from polycrystalline to monocrystalline through solid-phase-epitaxial growth, fundamentally altering the material parameters to eliminate grain boundaries and improve carrier mobility, thereby maintaining high on-off ratio at miniaturized dimensions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies selective oxidation to create a thin oxide layer only at the surface of the monocrystalline silicon layer, providing localized electrical control and enabling stable transistor operation at small channel lengths while maintaining high integration density

Inventive Principle:
Principle #3Local quality

2Shape

If a silicon layer is formed on an insulating film, then the SOI structure is achieved, but the crystallinity deteriorates due to difficulty in forming large-area silicon layer with good crystallinity

Engineering Contradiction:
ImproveSOI structureVSAvoidcrystallinity
Core Design Contradiction:
ShapeVSManufacturing precision

Solution Approach 1:

The patent performs preliminary formation of an amorphous silicon layer on the insulating film before applying solid-phase-epitaxial growth, creating a uniform base layer that enables subsequent monocrystallization and ensures large-area coverage with consistent crystallinity

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes the phase transition from amorphous to monocrystalline silicon through controlled solid-phase-epitaxial growth, transforming the material structure to achieve high crystallinity across large areas on the insulating film substrate

Inventive Principle:
Principle #36Phase transitions

3Manufacturing precision

If solid-phase-epitaxial growth is used, then the monocrystalline structure is formed, but surface non-conformity develops on the buried insulating film

Engineering Contradiction:
Improvemonocrystalline structureVSAvoidsurface conformality
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

The patent introduces an amorphous silicon layer as an intermediary between the insulating film and the monocrystalline silicon layer, allowing the epitaxial growth to proceed uniformly and preventing direct contact that would cause surface non-conformity on the buried insulating film

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces direct mechanical contact between the silicon layer and insulating film with a chemically bonded amorphous silicon intermediate layer, eliminating surface non-conformity while maintaining the monocrystalline structure through solid-phase-epitaxial growth

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the formation of high-crystallinity silicon layers, reducing cell-to-cell variations and short channel effects, resulting in enhanced memory device performance with improved current characteristics and reduced erroneous operations.

Implementation Method 1

forming a monocrystalline silicon layer by changing the amorphous silicon thin film into a monocrystal in the <100> direction by solid-phase-growth, with the opening as a seed

Methodology Applied
Scientific EffectSolid-phase-epitaxial growth: Epitaxy

Implementation Method 2

forming an oxide film at the surface of the crystal layer by heat-treating the monocrystal layer in an oxidizing atmosphere

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS7842564B2Semiconductor memory device manufacturing method and semiconductor memory device
Publication Date: 2010.11.30 KIOXIA CORP
  • US7842564B2 patent drawing
  • US7842564B2 patent drawing
  • US7842564B2 patent drawing

AI summary

In a method of manufacturing a semiconductor memory device, an opening is made in a part of an insulating film formed on a silicon substrate. An amorphous silicon thin film is formed on the insulating film in which the opening has been made and inside the opening. Then, a monocrystal is solid-phase-grown in the amorphous silicon thin film, with the opening as a seed, thereby forming a monocrystalline silicon layer. Then, the monocrystalline silicon layer is heat-treated in an oxidizing atmosphere, thereby thinning the monocrystalline silicon layer and reducing the defect density. Then, a memory cell array is formed on the monocrystalline silicon layer which has been thinned and whose defect density has been reduced.