Ferroelectric Memory Cell Using MPB PZT Composition

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Solution Overview

Problem

Existing memory devices based on ferroelectric elements, such as those using Lead Zirconate Titanate (PZT) materials, face challenges in increasing the spatial density of memory cells, which has not been adequately addressed in the known art.

Innovation Solution

The use of Lead Zirconate Titanate (PZT) material with a composition corresponding to a morphotropic phase boundary (MPB) composition, where the parameter x is in the range of 0.52 to 0.56, and the fabrication of ferroelectric elements with a substrate layer like Gd3Ga5O12 to minimize misfit strain, enabling a higher number of accessible polarization states and increased data storage density.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional PZT materials are used in ferroelectric memory devices, then the basic memory function is achieved, but the spatial density of memory cells cannot be increased

Engineering Contradiction:
Improvespatial density of memory cellsVSAvoidnumber of accessible polarization states
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The patent changes the compositional parameter of PZT material to MPB composition (Pb(Zr x Ti 1-x)O3 where x is 0.52 to 0.56) to enable multiple polarization states. This parameter change transforms the material properties to achieve co-existing rhombohedral and monoclinic phases, providing 8 or more accessible polarization states instead of the conventional limited states, thereby increasing spatial density of memory cells.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structure by combining PZT ferroelectric material with specific substrate materials (such as Gd3Ga5O12) to minimize misfit strain. This composite approach enables the ferroelectric element to maintain stable multiple polarization states, achieving higher spatial density without compromising material reliability.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If higher spatial density is achieved through material composition changes, then data storage capacity increases, but manufacturing precision requirements increase

Engineering Contradiction:
Improvedata storage densityVSAvoidcontrol of ferroelectric element composition and substrate alignment
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent specifies precise compositional parameters (x = 0.52 to 0.56 for MPB PZT) to achieve the desired multiple polarization states. By defining this specific parameter range, the patent balances the need for high data storage density with manufacturability, as this composition range provides robust multi-state behavior while being achievable through standard thin-film deposition techniques.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces substrate layers (such as Gd3Ga5O12) as intermediaries between the silicon substrate and the PZT ferroelectric layer. These substrate layers act as buffer layers that minimize misfit strain, thereby reducing the precision requirements for direct epitaxial growth and making the manufacturing process more feasible while maintaining high data storage density.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Speed

If conventional ferroelectric elements are used, then simple structure is maintained, but writing speed and power consumption are suboptimal

Engineering Contradiction:
Improvewriting speedVSAvoidpower consumption during write operation
Core Design Contradiction:
SpeedVSUse of energy by moving object

Solution Approach 1:

The patent changes the ferroelectric material parameter to MPB composition, which provides lower coercive field and easier polarization switching. This enables faster writing speed because less time and energy are required to switch between polarization states. The material composition change directly improves writing speed while the multi-state capability allows for efficient encoding schemes that reduce overall power consumption.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for a significant increase in the spatial density of memory cells, enabling faster writing speeds, lower power consumption, and the ability to store data using lower operating voltages, while maintaining high endurance and rapid read/write capabilities.

Implementation Method 1

the at least one ferroelectric element is fabricated from Lead Zirconate Titanate material whose composition corresponds to a morphotropic phase boundary composition... enabling a higher number of accessible polarization states

Methodology Applied
Scientific EffectFerroelectric effect:

Implementation Method 2

the at least one ferroelectric element is grown upon a substrate layer exposed to the at least one ferroelectric element, wherein the substrate layer is chosen to avoid misfit strain with the ferroelectric material

Methodology Applied
Scientific EffectStrain minimization through lattice matching:

Data Source

PatentEP2865007B1Ferroelectric memory device and manufacturing method thereof
Publication Date: 2019.11.20 FRANTTI JOHANNES
  • EP2865007B1 patent drawingFigure 1A
  • EP2865007B1 patent drawingFigure 1B
  • EP2865007B1 patent drawingFigure 2A~2C

AI summary

A memory device (700) for storing data includes at least one memory cell, and wherein the at least one memory cell includes at least one ferroelectric element (710) therein for storing data therein by way of one or more polarization directions of the at least ferroelectric element. The at least one ferroelectric element is fabricated comprises a ferroelectric material having a plurality of co¬ existing phases. Optionally, the at least one ferroelectric element is fabricated from Lead Zirconate Titanate material whose composition corresponds to a morphotropic phase boundary composition. More optionally, the Lead Zirconate Titanate material has a composition Pb(ZrxTi1-x)O3, wherein a parameter x is in a range of 0.52 to 0.56. The at least one ferroelectric element is provided with an electrode arrangement (720) which enables the at least one ferroelectric element to store a plurality of bits of data.