Magnetic Tunnel Junction Interface Control via Inverted Deposition

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Solution Overview

Problem

Conventional methods for manufacturing magnetic tunnel junction devices face challenges in controlling the interface structure between metal ferromagnetic and oxide layers, leading to difficulties in maintaining perpendicular magnetic anisotropy and coherent tunneling, which affects the thermal stability and data retention of magnetic memory devices.

Innovation Solution

A method involving the lamination of metallic oxide and metallic layers followed by heat treatment to transform these layers into ferromagnetic material and oxide layers, respectively, improving the interface quality and enhancing perpendicular magnetic anisotropy and coherent tunneling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional sputtering methods are used to deposit metal ferromagnetic and oxide layers, then the basic layered structure is formed, but the interface structure cannot be controlled and atomic-level separation is difficult to achieve

Engineering Contradiction:
Improveinterface structure controlVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by depositing the oxide layer first before the metal ferromagnetic layer, establishing the correct sequence from the beginning of the deposition process. This preliminary arrangement of layers prevents interface mixing and enables atomic-level separation without requiring complex additional processing steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes parameter changes by controlling the deposition conditions (such as sputtering power, gas flow rates, and deposition temperature) to achieve precise control over the interface structure. By adjusting these parameters, the process achieves atomic-level separation while maintaining manufacturing feasibility.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the oxide layer is deposited on the metal ferromagnetic layer, then the tunnel barrier structure is formed, but the metal layer is easily oxidized and ferromagnetic properties are lost

Engineering Contradiction:
Improveferromagnetic property maintenanceVSAvoidmetal oxidation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies inversion by reversing the conventional deposition sequence: instead of depositing metal first and then oxide, it deposits oxide first and then metal. This inverted sequence prevents the metal from being exposed to oxidizing conditions during the oxide deposition process, thereby maintaining ferromagnetic properties while forming the tunnel barrier structure.

Inventive Principle:
Principle #13The other way round (Inversion)

Solution Approach 2:

The patent applies preliminary anti-action by establishing the oxide layer as a protective barrier before depositing the metal ferromagnetic layer. This preliminary arrangement prevents oxygen from reaching and oxidizing the metal layer during subsequent processing, counteracting the harmful oxidation effect before it can occur.

Inventive Principle:
Principle #9Preliminary anti-action

3Reliability

If the oxide layer loses oxygen to the metal ferromagnetic layer, then the oxide is reduced and cannot operate as a tunnel layer, but this creates oxide defects that break coherent tunneling

Engineering Contradiction:
Improvetunnel layer functionalityVSAvoidoxide layer composition control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by depositing the oxide layer with controlled composition and structure before metal deposition. This preliminary preparation ensures the oxide layer has the appropriate oxygen content and crystalline structure to function as an effective tunnel barrier, preventing oxygen loss during subsequent processing.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes parameter changes by optimizing deposition parameters (such as oxygen partial pressure, deposition temperature, and layer thickness) to achieve precise control over the oxide layer's oxygen content and stoichiometry. This ensures the oxide layer maintains its tunneling functionality while preventing reduction reactions.

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If the amount of oxygen in the oxide layer is increased, then the metal ferromagnetic layer is oxidized and loses spin polarization, but if oxygen is decreased, then the oxide layer does not act as a tunnel layer

Engineering Contradiction:
Improveoxygen amount controlVSAvoidcoherent tunneling
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies parameter changes by precisely controlling deposition parameters (oxygen partial pressure, deposition rate, temperature) to achieve the optimal oxygen content in the oxide layer. This controlled parameter adjustment ensures sufficient oxygen for tunneling functionality while preventing excessive oxygen that would oxidize the metal layer.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by creating distinct regions with different oxygen concentrations: the oxide layer maintains high oxygen content for tunneling, while the metal ferromagnetic layer remains oxygen-free to preserve spin polarization. This local differentiation is achieved through the inverted deposition sequence and controlled interface formation.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach increases the thickness margin of the ferromagnetic material layer with perpendicular magnetic anisotropy, improves data retention, and enhances the quality of the interface between layers, leading to increased output and thermal stability of magnetic tunnel junction devices.

Implementation Method 1

A method involving the lamination of metallic oxide and metallic layers followed by heat treatment to transform these layers into ferromagnetic material and oxide layers, respectively

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 2

heat-treating the layered (or laminated) initial device... at least one metallic oxide layer and the metallic layer are converted to at least one ferromagnetic material layer and the oxide layer by heat treatment

Methodology Applied
Scientific EffectPhase transformation: Phase Change

Implementation Method 3

The metal ferromagnetic material layer needs to have perpendicular magnetic anisotropy to have strong thermal stability required for a memory device

Methodology Applied
Scientific EffectPerpendicular magnetic anisotropy: Anisotropy

Implementation Method 4

A magnetic tunnel junction device includes a first ferromagnetic material layer, a second ferromagnetic material layer, and an oxide layer

Methodology Applied
Scientific EffectFerromagnetism: Ferromagnetism

Implementation Method 5

the spin polarization of a ferromagnetic metal is maintained and tunneled to interact with the spin polarization of the other metal

Methodology Applied
Scientific EffectCoherent tunneling:

Implementation Method 6

The oxide layer 122 and the metal ferromagnetic material layer 132 are sequentially deposited on the lower electrode metal ferromagnetic layer 112 thereof to make a magnetic tunnel junction device 10 having the structure of the metal ferromagnetic material layer 112/tunnel barrier oxide layer 122/metal ferromagnetic material layer 132

Methodology Applied
Scientific EffectTunnel barrier:

Data Source

PatentUS12041854B2Magnetic tunnel junction device, magnetic memory using the same and method for manufacturing the same
Publication Date: 2024.07.16 UI (UNIVERSITY IND FOUNDATION) YONSEI UNIVERSITY
  • US12041854B2 patent drawing
  • US12041854B2 patent drawing
  • US12041854B2 patent drawing

AI summary

Disclosed art a magnetic tunnel junction device, a magnetic memory using the same, and a method for manufacturing the same. The method for manufacturing the magnetic tunnel junction device may include the steps of a lamination step of forming an initial multilayer structure including at least one metallic oxide layer and a metallic layer on a substrate; a heat treatment step of heat-treating the initial multilayer structure; and a device forming step of forming a magnetic tunnel junction device of a final multilayer structure in which at least one metallic oxide layer and the metallic layer are converted to at least one ferromagnetic material layer and the oxide layer by heat treatment.