Magnetic Tunnel Junction Protection Layers Mitigate Oxidation

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Magnetic tunnel junction (MTJ) structures face oxidation issues during the deposition process, leading to reduced current flow and potential memory cell failure due to the oxidation of ferro-magnetic layers.

Innovation Solution

Incorporating protection layers between the magnetic reference and storage layers and between these layers and the capping layer, made from materials different from the ferro-magnetic layers, to prevent oxidation during deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If tunnel barrier layer and capping layer are deposited over ferro-magnetic layers, then MTJ stack structure is formed, but ferro-magnetic layers undergo oxidation leading to memory cell failure

Engineering Contradiction:
Improvememory cell reliabilityVSAvoidoxidation of ferro-magnetic layers
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

A protection layer comprising aluminum is deposited between the tunnel barrier layer and the first ferro-magnetic layer, and between the capping layer and the second ferro-magnetic layer. This intermediary protection layer prevents direct contact and oxidation of the ferro-magnetic layers during the deposition process, thereby resolving the contradiction between forming the MTJ stack structure and preventing oxidation of the ferro-magnetic layers

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The protection layer creates an inert environment for the ferro-magnetic layers during deposition. By placing the aluminum-based protection layer between the ferro-magnetic layers and the deposition process, it establishes a protective barrier that prevents oxidizing conditions from reaching the sensitive ferro-magnetic materials, thus maintaining their integrity while allowing the MTJ stack to be formed

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Object-affected harmful factors

If protection layers are added to prevent oxidation, then ferro-magnetic layers are protected from oxidation, but device structure becomes more complex

Engineering Contradiction:
Improveoxidation preventionVSAvoidMTJ stack structure complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The protection layer is implemented as a thin film structure comprising aluminum, deposited in specific locations within the MTJ stack. This thin film approach provides effective oxidation protection while minimizing the increase in structural complexity and overall device dimensions, as the protection is achieved through nanoscale thin layers rather than bulky protective structures

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The protection layers effectively mitigate oxidation, maintaining high current flow and preventing memory cell failure by isolating the ferro-magnetic layers from oxidizing during the deposition of other layers in the MTJ stack.

Implementation Method 1

one or more of the ferro-magnetic layers may be oxidized. The oxidation alters the electrical resistance and magnetic properties

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS11522126B2Magnetic tunnel junctions with protection layers
Publication Date: 2022.12.06 APPLIED MATERIALS INC
  • US11522126B2 patent drawing
  • US11522126B2 patent drawing
  • US11522126B2 patent drawing

AI summary

A film stack for a magnetic tunnel comprises a substrate, a magnetic reference layer disposed over the substrate, and a tunnel barrier layer disposed over the magnetic reference layer. The film stack further comprises a magnetic storage layer disposed over the tunnel barrier layer, and a capping layer disposed over the magnetic storage layer. Further, the film stack comprises at least one protection layer disposed between the magnetic reference layer and the tunnel barrier layer and disposed between the magnetic storage layer and the capping layer. Additionally, a material forming the at least one protection layer differs from at least one of a material forming the magnetic reference layer and a material forming the magnetic storage layer.