Magnetic Tunnel Junction Memory Devices Using Resonant Tunneling

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Solution Overview

Problem

Magnetoresistive memory devices face challenges in efficiently programming and maintaining the magnetization states of ferromagnetic layers due to limitations in external power sources and spin transfer mechanisms, which affect the reliability and efficiency of data storage.

Innovation Solution

The implementation of a magnetic tunnel junction structure with a ferromagnetic reference layer, a ferromagnetic free layer, and multiple tunneling dielectric layers, including textured magnesium oxide and spinel materials, along with a voltage-controlled exchange coupling layer stack and spin-orbit-torque mechanisms, to enhance resonant tunneling and exchange coupling, thereby improving magnetization control and tunneling magnetoresistance ratios.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional spin transfer mechanisms are used to flip magnetization direction, then programming can be achieved, but the reliability and efficiency of data storage are compromised

Engineering Contradiction:
Improvemagnetization switching reliabilityVSAvoidprogramming efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the physical parameters of the tunneling dielectric layer, specifically introducing a double barrier structure with specific thicknesses (first barrier: 1-3 nm, second barrier: 0.5-2 nm) and material compositions. This parameter optimization enables resonant tunneling effects that significantly improve both the reliability of magnetization switching and the programming efficiency, resolving the contradiction between these two parameters.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures including double barrier tunneling dielectric layers with different materials (e.g., MgO and Al2O3), ferromagnetic layers with specific compositions (CoFeB, CoFe), and nonmagnetic spacer layers. These composite structures create quantum well states that enhance resonant tunneling, simultaneously improving switching reliability and programming efficiency.

Inventive Principle:
Principle #40Composite materials

2Productivity

If external power sources are used for programming, then magnetization direction can be flipped, but the efficiency is limited

Engineering Contradiction:
Improveprogramming efficiencyVSAvoidpower consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent replaces traditional external power source mechanisms (electromagnetic fields, spin transfer torque) with a quantum mechanical tunneling mechanism. By designing double barrier tunneling dielectric layers that create resonant tunneling conditions, the system achieves efficient magnetization switching through quantum effects rather than conventional power-intensive methods, improving programming efficiency while reducing power consumption.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes quantum phase transitions in the tunneling dielectric barriers, specifically engineering the barrier heights and thicknesses to create resonant tunneling states. This quantum phase behavior allows for highly efficient electron transport control, enabling low-power programming with high efficiency by exploiting quantum mechanical effects rather than thermal or electromagnetic processes.

Inventive Principle:
Principle #36Phase transitions

3Reliability

If single barrier tunneling dielectric is used, then structure is simple, but tunneling magnetoresistance ratio is insufficient

Engineering Contradiction:
Improvetunneling magnetoresistance ratioVSAvoidtunneling dielectric structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent segments the single tunneling dielectric barrier into a double barrier structure, dividing it into two distinct barriers with different materials and thicknesses. This segmentation creates quantum well states between the barriers, enabling resonant tunneling that significantly enhances the tunneling magnetoresistance ratio. The first barrier (1-3 nm) and second barrier (0.5-2 nm) work synergistically to achieve high TMR while maintaining manageable structural complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces a ferromagnetic quantum well layer as an intermediary between the two tunneling barriers. This intermediary layer with specific thickness (0.5-2 nm) creates quantized energy states that mediate the tunneling process, enabling resonant tunneling conditions. The quantum well acts as a mediator that enhances electron transport selectivity based on spin direction, significantly improving TMR ratio despite the increased structural complexity of the double barrier system.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration significantly increases tunneling magnetoresistance ratios and improves the reliability of magnetization switching, leading to enhanced data storage capabilities and efficiency in magnetoresistive memory devices.

Implementation Method 1

magnetic tunnel junction memory devices employing resonant electron tunneling

Methodology Applied
Scientific EffectResonant tunneling:

Implementation Method 2

At least one of the reference layer or the free layer comprises a quantum well

Methodology Applied
Scientific EffectQuantum well:

Implementation Method 3

Programming of the magnetoresistive memory device requires flipping of the direction of the magnetization of the free layer employing various external power sources, which may be magnetic in nature or may employ a spin transfer mechanism

Methodology Applied
Scientific EffectSpin transfer torque:

Implementation Method 4

voltage controlled exchange coupling layer stack comprising a perpendicular magnetic anisotropy (PMA) ferromagnetic layer having a fixed magnetization direction, a ferromagnetic free layer, and an electrically conductive nonmagnetic interlayer exchange coupling layer located between the free layer and the PMA ferromagnetic layer and providing voltage dependent exchange coupling

Methodology Applied
Scientific EffectExchange coupling:

Implementation Method 5

a spin Hall effect metal line contacting a surface of the free layer

Methodology Applied
Scientific EffectSpin Hall effect:

Data Source

PatentUS11349066B2Magnetic tunnel junction memory devices employing resonant tunneling and methods of manufacturing the same
Publication Date: 2022.05.31 SANDISK TECHNOLOGIES LLC
  • US11349066B2 patent drawing
  • US11349066B2 patent drawing
  • US11349066B2 patent drawing

AI summary

A magnetoresistive memory device includes a magnetic tunnel junction including a free layer, at least two tunneling dielectric barrier layers, and at least one metallic quantum well layer. The quantum well layer leads to the resonant electron tunneling through the magnetic tunnel junction in such a way that it strongly enhances the tunneling probability for one of the magnetization states of the free layer, while this tunneling probability remains much smaller in the opposite magnetization state of the free layer. The device can be configured in a spin transfer torque device configuration, a voltage-controlled magnetic anisotropy, a voltage controlled exchange coupling device configuration, or a spin-orbit-torque device configuration.