Multilayer Capacitor Electrode Structure for Moisture Resistance

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Solution Overview

Problem

Multilayer ceramic capacitors face issues with reduced high-temperature insulation resistance and moisture resistance reliability due to alloy formation between internal and external electrodes, blister defects from residual carbon, and glass elution, which affect bonding strength and capacitance per unit volume.

Innovation Solution

The multilayer electronic component design includes specific area and thickness ratios for glass in external electrodes, ensuring S1-2>S1-1, S2-2>S2-1, T1-2≤8 μm, and T2-2≤8 μm, to prevent alloy formation, glass elution, and facilitate residual carbon discharge, thereby enhancing moisture resistance and bonding strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If glass is added to the external electrode to improve bonding strength, then bonding strength between body and external electrode is improved, but glass may be eluted to the outer surface causing reliability issues

Engineering Contradiction:
Improvebonding strengthVSAvoidmoisture resistance reliability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies different glass content levels to different regions of the external electrode. The side surface electrode layer has a first glass content (higher) for bonding strength, while the upper surface electrode layer has a second glass content (lower) to prevent elution. This local differentiation resolves the contradiction between bonding strength and moisture resistance.

Inventive Principle:
Principle #3Local quality

2Strength

If external electrode thickness is increased to improve bonding strength, then bonding strength is improved, but capacitance per unit volume decreases and blisters form due to residual carbon

Engineering Contradiction:
Improvebonding strengthVSAvoidcapacitance per unit volume
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent differentiates the thickness and glass content of electrode layers based on their location. The side surface electrode layer has greater thickness and higher glass content for bonding, while the upper surface electrode layer has reduced thickness and lower glass content to prevent blisters and maintain capacitance density. This resolves the contradiction between bonding strength and capacitance per unit volume.

Inventive Principle:
Principle #3Local quality

3Strength

If glass content in external electrode is increased to improve bonding strength, then bonding strength is improved, but residual carbon cannot be discharged causing blisters

Engineering Contradiction:
Improvebonding strengthVSAvoidblisters
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent controls glass content locally in different electrode layers. The side surface electrode layer contains sufficient glass for bonding strength, while the upper surface electrode layer has reduced glass content (second glass content < first glass content) to enable proper carbon discharge during firing and prevent blister formation.

Inventive Principle:
Principle #3Local quality

4Reliability

If dielectric layer thickness is reduced to increase capacitance per unit volume, then capacitance per unit volume is improved, but bonding strength and reliability may be compromised

Engineering Contradiction:
Improvecapacitance per unit volumeVSAvoidbonding strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent compensates for reduced dielectric layer thickness by optimizing the external electrode structure. Different electrode layers have differentiated glass content and thickness, with the side surface electrode providing enhanced bonding through higher glass content, thereby maintaining bonding strength even when dielectric layer thickness is reduced to increase capacitance density.

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS12462981B2Multilayer electronic component
Publication Date: 2025.11.04 SAMSUNG ELECTRO MECHANICS CO LTD
  • US12462981B2 patent drawing
  • US12462981B2 patent drawing
  • US12462981B2 patent drawing

AI summary

A multilayer electronic component includes a body including a dielectric layer and first and second internal electrodes and including first and second surfaces, third and fourth surfaces, and fifth and sixth surfaces, a first external electrode including a 1-1-th electrode layer disposed on the third surface, and a 1-2-th electrode layer disposed on the first and second surfaces, a second external electrode including a 2-1-th electrode layer disposed on the fourth surface, and a 2-2-th electrode layer disposed on the first and second surfaces, wherein S1-2&gt;S1-1, T1-2≤8 μm, S2-2&gt;S2-1, and T2-2≤8 μm where based on a cross section of the first and second external electrodes, S1-1, S1-2, S2-1, S2-2 are fractions of an area occupied by glass in the 1-1-th, 1-2-th, 2-1-th, and 2-2-th electrode layers, respectively, T1-2 and T2-2 are thicknesses of the 1-2-th and 2-2-th electrode layers, respectively.